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. 2018 Oct 26;42(8):518–524. doi: 10.1093/jat/bky055

Table I.

MRM conditions and compensation voltages for cocaine and its metabolites

Compound Transition ions (m/z) DP (V) CE (V) CoV (V) Elution time (Min)
COC 304.1 > 182.2 38 28 −15.5 0.73
COC-d3 307.1 > 185.2 38 28 −15.5 0.73
BE 290.1 > 168.1 37 28 −19.8 0.60
290.1 > 105.1 37 35 −19.8 0.60
BE-d8 298.1 > 171.1 37 28 −19.8 0.60
398.1 > 110.1 37 35 −19.8 0.60
EME 200.1 > 182.2 35 26 −31.4 0.18
200.1 > 82.1 35 39 −31.4 0.18
EME-d3 203.1 > 185.2 35 26 −31.4 0.18
203.1 > 85.1 35 39 −31.4 0.18
CE 318.1 > 196.2 45 25 −13.2 0.81
318.1 > 82.2 45 50 −13.2 0.81
CE-d8 326.1 > 204.1 45 25 −13.2 0.81
326.1 > 85.2 45 50 −13.2 0.81

DP, deprotonation energy; CE, collision energy CoV, compensation voltage.