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. 2018 Oct 1;11(10):1865. doi: 10.3390/ma11101865
Latin
ab specific area of the bed (m2/m3)
ac activity of carbon
ct total molar concentration of the gas (mol m−3)
cpg molar specific heat of the gas (J mol−1 K−1)
cps mass specific heat of the solid (J kg−1 K−1)
dp pellet diameter (m)
D diffusion or dispersion (Da, Dr) coefficient (m2/s)
h heat transfer coefficient (W m−2 K−1)
H height of the cylindrical section of the shaft (m)
Hfeed gas height of the reducing gas inlet (m)
Hinf height of the conical section of the shaft (m)
Keq equilibrium constant
K permeability coefficient (kg m−3 s−1)
k mass transfer coefficient, or reaction rate constant
M molar weight (kg mol−3)
p gas pressure
Pi partial pressure of component i (bar)
r radius (m)
R ideal gas constant (J mol−1 K−1)
S source term
T temperature (K)
u velocity (m s−1)
v reaction rate (mol m−3 s−1)
wj mass fraction of solid j
X degree of conversion
xi molar fraction of i in the gas
z height (m)
Greek
ΔrH heat of reaction (J mol−1)
ε porosity
τ characteristic time (s)
λ thermal conductivity (W m−1 K−1)
µg viscosity of the gas (Pa s)
ρg mass density of the gas (kg m−3)
ρb mass density of the bed (kg mbed3)
ρ˜j molar density of species j in the bed (mol mbed3)
Subscripts
b bed
c catalyst
cryst crystallite
chem chemical
diff diffusional
interg intergranular
ini initial
intrac intra-crystallite
interc inter-crystallite
in the bulk gas
eff effective (for the bed)
eq at equilibrium
g gas
grain grain
p pellet
r radial
s solid
z axial