| C1—N1 | 1.311 (3) | C8—H9 | 0.9800 |
| C1—N2 | 1.337 (4) | C8—H10 | 0.9800 |
| C1—C2 | 1.444 (4) | C9—H11 | 0.9800 |
| C2—C3 | 1.192 (4) | C9—H12 | 0.9800 |
| C3—C4 | 1.428 (4) | C9—H13 | 0.9800 |
| C4—C5 | 1.498 (4) | C10—N2 | 1.465 (3) |
| C4—C6 | 1.498 (5) | C10—C11 | 1.491 (5) |
| C4—H2 | 1.0000 | C10—C12 | 1.494 (4) |
| C5—C6 | 1.461 (6) | C10—H14 | 1.0000 |
| C5—H4 | 0.9900 | C11—H15 | 0.9800 |
| C5—H3 | 0.9900 | C11—H16 | 0.9800 |
| C6—H5 | 0.9900 | C11—H17 | 0.9800 |
| C6—H6 | 0.9900 | C12—H18 | 0.9800 |
| C7—N1 | 1.473 (3) | C12—H19 | 0.9800 |
| C7—C9 | 1.512 (4) | C12—H20 | 0.9800 |
| C7—C8 | 1.521 (5) | Cl—Mn | 2.3556 (8) |
| C7—H7 | 1.0000 | N1—Mn | 2.160 (2) |
| C8—H8 | 0.9800 | N2—H1 | 0.85 (2) |
| N1—C1—N2 | 122.2 (2) | C7—C9—H12 | 109.5 |
| N1—C1—C2 | 122.2 (2) | H11—C9—H12 | 109.5 |
| N2—C1—C2 | 115.7 (2) | C7—C9—H13 | 109.5 |
| C3—C2—C1 | 177.2 (3) | H11—C9—H13 | 109.5 |
| C2—C3—C4 | 177.5 (3) | H12—C9—H13 | 109.5 |
| C3—C4—C5 | 120.7 (3) | N2—C10—C11 | 111.6 (3) |
| C3—C4—C6 | 120.1 (3) | N2—C10—C12 | 109.1 (2) |
| C5—C4—C6 | 58.4 (2) | C11—C10—C12 | 111.9 (3) |
| C3—C4—H2 | 115.3 | N2—C10—H14 | 108.1 |
| C5—C4—H2 | 115.3 | C11—C10—H14 | 108.1 |
| C6—C4—H2 | 115.3 | C12—C10—H14 | 108.1 |
| C6—C5—C4 | 60.8 (2) | C10—C11—H15 | 109.5 |
| C6—C5—H4 | 117.7 | C10—C11—H16 | 109.5 |
| C4—C5—H4 | 117.7 | H15—C11—H16 | 109.5 |
| C6—C5—H3 | 117.7 | C10—C11—H17 | 109.5 |
| C4—C5—H3 | 117.7 | H15—C11—H17 | 109.5 |
| H4—C5—H3 | 114.8 | H16—C11—H17 | 109.5 |
| C5—C6—C4 | 60.8 (2) | C10—C12—H18 | 109.5 |
| C5—C6—H5 | 117.7 | C10—C12—H19 | 109.5 |
| C4—C6—H5 | 117.7 | H18—C12—H19 | 109.5 |
| C5—C6—H6 | 117.7 | C10—C12—H20 | 109.5 |
| C4—C6—H6 | 117.7 | H18—C12—H20 | 109.5 |
| H5—C6—H6 | 114.8 | H19—C12—H20 | 109.5 |
| N1—C7—C9 | 110.3 (2) | C1—N1—C7 | 117.6 (2) |
| N1—C7—C8 | 110.1 (3) | C1—N1—Mn | 125.95 (18) |
| C9—C7—C8 | 111.4 (3) | C7—N1—Mn | 116.44 (16) |
| N1—C7—H7 | 108.3 | C1—N2—C10 | 126.9 (2) |
| C9—C7—H7 | 108.3 | C1—N2—H1 | 116 (2) |
| C8—C7—H7 | 108.3 | C10—N2—H1 | 117 (2) |
| C7—C8—H8 | 109.5 | N1—Mn—N1i | 113.06 (13) |
| C7—C8—H9 | 109.5 | N1—Mn—Cl | 106.62 (6) |
| H8—C8—H9 | 109.5 | N1i—Mn—Cl | 112.79 (6) |
| C7—C8—H10 | 109.5 | N1—Mn—Cli | 112.80 (6) |
| H8—C8—H10 | 109.5 | N1i—Mn—Cli | 106.62 (6) |
| H9—C8—H10 | 109.5 | Cl—Mn—Cli | 104.74 (5) |
| C7—C9—H11 | 109.5 | ||
| C3—C4—C5—C6 | −108.6 (4) | C8—C7—N1—C1 | −100.7 (3) |
| C3—C4—C6—C5 | 109.7 (3) | C9—C7—N1—Mn | −42.7 (3) |
| N2—C1—N1—C7 | 176.0 (3) | C8—C7—N1—Mn | 80.7 (2) |
| C2—C1—N1—C7 | −3.8 (4) | N1—C1—N2—C10 | 167.7 (3) |
| N2—C1—N1—Mn | −5.5 (4) | C2—C1—N2—C10 | −12.5 (4) |
| C2—C1—N1—Mn | 174.66 (19) | C11—C10—N2—C1 | 104.8 (4) |
| C9—C7—N1—C1 | 135.9 (3) | C12—C10—N2—C1 | −131.2 (3) |