Crystal structures of the [IrIII{C(C4H6O2)(dppm)-κ3 P,C,O}(dppm)H](CF3O3S)2 and [IrIII{C(C4H6O2)(dppm)-κ2 P,C}(CO)(dppm)H](CF3O3S)2 phosphorus ylide complexes, generated by a Wittig-type carbon–carbon coupling reaction of a carbodiphospho­rane PCP ligand system

. 2018 Oct 23;74(Pt 11):1643–1647. doi: 10.1107/S205698901801455X

[IrH(C₃₀H₂₈O₂P₂)(C₂₅H₂₂P₂)](CF₃O₃S)₂	D_x = 1.593 Mg m⁻³
M_r = 1358.17	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, P2₁2₁2₁	Cell parameters from 83772 reflections
a = 11.3249 (1) Å	θ = 1.0–25.3°
b = 21.3629 (3) Å	µ = 2.62 mm⁻¹
c = 23.4125 (3) Å	T = 233 K
V = 5664.25 (12) Å³	Prism, colorless
Z = 4	0.41 × 0.05 × 0.04 mm
F(000) = 2720