Table 2. Experimental details.

Crystal data
Chemical formula	C14H16S4 +·I3 −
M r	693.21
Crystal system, space group	Triclinic, P
Temperature (K)	293
a, b, c (Å)	8.4334 (1), 12.1857 (2), 14.9874 (3)
α, β, γ (°)	90.063 (1), 94.279 (1), 104.063 (1)
V (Å3)	1489.59 (4)
Z	3
Radiation type	Mo Kα
μ (mm−1)	5.13
Crystal size (mm)	0.21 × 0.20 × 0.03
Data collection
Diffractometer	Nonius KappaCCD
Absorption correction	Analytical (Alcock, 1970 ▸)
T min, T max	0.375, 0.859
No. of measured, independent and observed [I > 2σ(I)] reflections	30936, 6630, 4525
R int	0.064
(sin θ/λ)max (Å−1)	0.651
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.031, 0.066, 1.01
No. of reflections	6630
No. of parameters	287
H-atom treatment	H-atom parameters constrained
Δρmax, Δρmin (e Å−3)	0.60, −0.58

Computer programs: COLLECT (Nonius, 1998 ▸), HKL, DENZO and SCALEPACK (Otwinowski & Minor, 1997 ▸), SHELXT2014 (Sheldrick, 2015a ▸), SHELXL2016 (Sheldrick, 2015b ▸), WinGX (Farrugia, 2012 ▸), DIAMOND (Brandenburg, 2006 ▸), publCIF (Westrip, 2010 ▸) and enCIFer (Allen et al., 2004 ▸).