| Zn1—N2 | 2.0622 (13) | C20—C21 | 1.374 (3) |
| Zn1—N2i | 2.0622 (13) | C20—H20 | 0.9500 |
| Zn1—N1i | 2.0684 (14) | C21—C22 | 1.376 (3) |
| Zn1—N1 | 2.0685 (14) | C21—H21 | 0.9500 |
| Zn1—O1 | 2.1352 (19) | C22—C23 | 1.387 (3) |
| N1—C4 | 1.368 (2) | C22—H22 | 0.9500 |
| N1—C1 | 1.370 (2) | C23—H23 | 0.9500 |
| N2—C9 | 1.368 (2) | N4—C24 | 1.162 (3) |
| N2—C6 | 1.370 (2) | C24—S2 | 1.571 (2) |
| C1—C10i | 1.397 (2) | O1—C31 | 1.436 (2) |
| C1—C2 | 1.443 (2) | O1—C31i | 1.436 (2) |
| C2—C3 | 1.348 (2) | C31—C32 | 1.507 (3) |
| C2—H2 | 0.9500 | C31—H31A | 0.9900 |
| C3—C4 | 1.440 (2) | C31—H31B | 0.9900 |
| C3—H3 | 0.9500 | C32—H32A | 0.9800 |
| C4—C5 | 1.401 (2) | C32—H32B | 0.9800 |
| C5—C6 | 1.404 (2) | C32—H32C | 0.9800 |
| C5—C11 | 1.494 (2) | O2—C42ii | 1.11 (2) |
| C6—C7 | 1.440 (2) | O2—C42 | 1.479 (12) |
| C7—C8 | 1.355 (3) | O2—C43 | 1.495 (11) |
| C7—H7 | 0.9500 | O2—C41ii | 1.912 (18) |
| C8—C9 | 1.440 (2) | C41—C44ii | 0.755 (17) |
| C8—H8 | 0.9500 | C41—C43ii | 0.900 (18) |
| C9—C10 | 1.401 (2) | C41—C42 | 1.499 (14) |
| C10—C1i | 1.397 (2) | C41—O2ii | 1.912 (18) |
| C10—C18 | 1.494 (2) | C41—H41A | 0.9600 |
| C11—C16 | 1.391 (3) | C41—H41B | 0.9599 |
| C11—C12 | 1.398 (3) | C41—H41C | 0.9600 |
| C12—C13 | 1.390 (3) | C42—C43ii | 0.703 (16) |
| C12—N3 | 1.393 (2) | C42—O2ii | 1.11 (2) |
| C13—C14 | 1.370 (3) | C42—C42ii | 1.92 (3) |
| C13—H13 | 0.9500 | C42—H42A | 0.9601 |
| C14—C15 | 1.384 (3) | C42—H42B | 0.9599 |
| C14—H14 | 0.9500 | C43—C42ii | 0.703 (16) |
| C15—C16 | 1.385 (3) | C43—C41ii | 0.900 (18) |
| C15—H15 | 0.9500 | C43—C44 | 1.446 (14) |
| C16—H16 | 0.9500 | C43—H43A | 0.9599 |
| N3—C17 | 1.170 (3) | C43—H43B | 0.9600 |
| C17—S1 | 1.576 (2) | C44—C41ii | 0.755 (17) |
| C18—C23 | 1.389 (3) | C44—H44A | 0.9600 |
| C18—C19 | 1.394 (3) | C44—H44B | 0.9600 |
| C19—N4 | 1.392 (3) | C44—H44C | 0.9599 |
| C19—C20 | 1.394 (3) | ||
| N2—Zn1—N2i | 164.44 (8) | C31—O1—Zn1 | 122.65 (11) |
| N2—Zn1—N1i | 88.85 (6) | C31i—O1—Zn1 | 122.65 (11) |
| N2i—Zn1—N1i | 88.54 (6) | O1—C31—C32 | 111.82 (17) |
| N2—Zn1—N1 | 88.54 (6) | O1—C31—H31A | 109.3 |
| N2i—Zn1—N1 | 88.85 (6) | C32—C31—H31A | 109.3 |
| N1i—Zn1—N1 | 160.61 (8) | O1—C31—H31B | 109.3 |
| N2—Zn1—O1 | 97.78 (4) | C32—C31—H31B | 109.3 |
| N2i—Zn1—O1 | 97.78 (4) | H31A—C31—H31B | 107.9 |
| N1i—Zn1—O1 | 99.69 (4) | C31—C32—H32A | 109.5 |
| N1—Zn1—O1 | 99.69 (4) | C31—C32—H32B | 109.5 |
| C4—N1—C1 | 106.50 (14) | H32A—C32—H32B | 109.5 |
| C4—N1—Zn1 | 126.59 (11) | C31—C32—H32C | 109.5 |
| C1—N1—Zn1 | 126.82 (11) | H32A—C32—H32C | 109.5 |
| C9—N2—C6 | 106.88 (13) | H32B—C32—H32C | 109.5 |
| C9—N2—Zn1 | 126.26 (11) | C42ii—O2—C42 | 94.7 (13) |
| C6—N2—Zn1 | 126.16 (11) | C42ii—O2—C43 | 26.4 (9) |
| N1—C1—C10i | 125.29 (15) | C42—O2—C43 | 120.3 (9) |
| N1—C1—C2 | 109.66 (14) | C42ii—O2—C41ii | 51.6 (8) |
| C10i—C1—C2 | 125.05 (16) | C42—O2—C41ii | 146.0 (10) |
| C3—C2—C1 | 106.91 (15) | C43—O2—C41ii | 27.3 (8) |
| C3—C2—H2 | 126.5 | C44ii—C41—C43ii | 122 (3) |
| C1—C2—H2 | 126.5 | C44ii—C41—C42 | 137 (3) |
| C2—C3—C4 | 107.20 (15) | C43ii—C41—C42 | 18.1 (13) |
| C2—C3—H3 | 126.4 | C44ii—C41—O2ii | 129 (2) |
| C4—C3—H3 | 126.4 | C43ii—C41—O2ii | 49.6 (12) |
| N1—C4—C5 | 125.53 (15) | C42—C41—O2ii | 35.6 (7) |
| N1—C4—C3 | 109.70 (14) | C44ii—C41—H41A | 60.7 |
| C5—C4—C3 | 124.76 (16) | C43ii—C41—H41A | 94.4 |
| C4—C5—C6 | 125.25 (16) | C42—C41—H41A | 110.3 |
| C4—C5—C11 | 117.74 (15) | O2ii—C41—H41A | 143.7 |
| C6—C5—C11 | 116.99 (15) | C44ii—C41—H41B | 114.2 |
| N2—C6—C5 | 125.30 (15) | C43ii—C41—H41B | 124.1 |
| N2—C6—C7 | 109.32 (15) | C42—C41—H41B | 108.7 |
| C5—C6—C7 | 125.28 (16) | O2ii—C41—H41B | 97.5 |
| C8—C7—C6 | 107.28 (16) | H41A—C41—H41B | 109.5 |
| C8—C7—H7 | 126.4 | C44ii—C41—H41C | 50.2 |
| C6—C7—H7 | 126.4 | C43ii—C41—H41C | 108.5 |
| C7—C8—C9 | 106.85 (15) | C42—C41—H41C | 109.4 |
| C7—C8—H8 | 126.6 | O2ii—C41—H41C | 82.6 |
| C9—C8—H8 | 126.6 | H41A—C41—H41C | 109.5 |
| N2—C9—C10 | 125.61 (15) | H41B—C41—H41C | 109.5 |
| N2—C9—C8 | 109.64 (15) | C43ii—C42—O2ii | 109 (2) |
| C10—C9—C8 | 124.73 (16) | C43ii—C42—O2 | 127 (2) |
| C1i—C10—C9 | 125.76 (16) | O2ii—C42—O2 | 20.8 (8) |
| C1i—C10—C18 | 116.90 (15) | C43ii—C42—C41 | 23 (2) |
| C9—C10—C18 | 117.33 (15) | O2ii—C42—C41 | 92.9 (12) |
| C16—C11—C12 | 117.55 (16) | O2—C42—C41 | 108.1 (13) |
| C16—C11—C5 | 120.98 (17) | C43ii—C42—C42ii | 156 (3) |
| C12—C11—C5 | 121.45 (16) | O2ii—C42—C42ii | 50.1 (8) |
| C13—C12—N3 | 117.92 (18) | O2—C42—C42ii | 35.3 (7) |
| C13—C12—C11 | 121.16 (18) | C41—C42—C42ii | 142.7 (10) |
| N3—C12—C11 | 120.92 (16) | C43ii—C42—H42A | 107.4 |
| C14—C13—C12 | 119.9 (2) | O2ii—C42—H42A | 132.6 |
| C14—C13—H13 | 120.0 | O2—C42—H42A | 112.6 |
| C12—C13—H13 | 120.0 | C41—C42—H42A | 109.5 |
| C13—C14—C15 | 120.15 (18) | C42ii—C42—H42A | 96.5 |
| C13—C14—H14 | 119.9 | C43ii—C42—H42B | 88.1 |
| C15—C14—H14 | 119.9 | O2ii—C42—H42B | 102.7 |
| C14—C15—C16 | 119.83 (18) | O2—C42—H42B | 109.6 |
| C14—C15—H15 | 120.1 | C41—C42—H42B | 108.8 |
| C16—C15—H15 | 120.1 | C42ii—C42—H42B | 86.7 |
| C15—C16—C11 | 121.34 (19) | H42A—C42—H42B | 108.1 |
| C15—C16—H16 | 119.3 | C42ii—C43—C41ii | 138 (3) |
| C11—C16—H16 | 119.3 | C42ii—C43—C44 | 158 (2) |
| C17—N3—C12 | 157.6 (2) | C41ii—C43—C44 | 26.4 (16) |
| N3—C17—S1 | 176.6 (2) | C42ii—C43—O2 | 44.9 (18) |
| C23—C18—C19 | 117.82 (16) | C41ii—C43—O2 | 103.2 (17) |
| C23—C18—C10 | 121.48 (16) | C44—C43—O2 | 113.4 (10) |
| C19—C18—C10 | 120.68 (17) | C42ii—C43—H43A | 83.7 |
| N4—C19—C20 | 119.79 (18) | C41ii—C43—H43A | 83.3 |
| N4—C19—C18 | 118.78 (16) | C44—C43—H43A | 102.7 |
| C20—C19—C18 | 121.44 (19) | O2—C43—H43A | 107.3 |
| C21—C20—C19 | 119.2 (2) | C42ii—C43—H43B | 86.1 |
| C21—C20—H20 | 120.4 | C41ii—C43—H43B | 135.5 |
| C19—C20—H20 | 120.4 | C44—C43—H43B | 111.5 |
| C20—C21—C22 | 120.49 (18) | O2—C43—H43B | 113.6 |
| C20—C21—H21 | 119.8 | H43A—C43—H43B | 107.3 |
| C22—C21—H21 | 119.8 | C41ii—C44—C43 | 32.0 (18) |
| C21—C22—C23 | 120.1 (2) | C41ii—C44—H44A | 115.3 |
| C21—C22—H22 | 119.9 | C43—C44—H44A | 111.3 |
| C23—C22—H22 | 119.9 | C41ii—C44—H44B | 82.6 |
| C22—C23—C18 | 120.90 (19) | C43—C44—H44B | 113.0 |
| C22—C23—H23 | 119.5 | H44A—C44—H44B | 109.5 |
| C18—C23—H23 | 119.5 | C41ii—C44—H44C | 126.1 |
| C24—N4—C19 | 161.5 (2) | C43—C44—H44C | 104.0 |
| N4—C24—S2 | 178.01 (19) | H44A—C44—H44C | 109.5 |
| C31—O1—C31i | 114.7 (2) | H44B—C44—H44C | 109.5 |