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. 2018 Sep 27;57(43):13968–13981. doi: 10.1002/anie.201804597

Table 2.

Thermodynamic hydration data for selected solutes.

kosmotropic
anion
chaotropic
anion
superchaotropic
anion
hydrophobic
ion
hydrophobic neutral
species
F SCN ClO4 B12H12 2− BPh4 AsPh4 + CH4
ΔG hyd [a] −112.1[b] −69.6[b] −54.7[b] −140[c] 10.8[b] 10.3[b] 2.0[d]
ΔH hyd [a] −121.9[b] −74.3[b] −58.8[b] −145[e] −11.2[b] −11.2[b] −2.6[d]
TΔS hyd [a] −9.8[b] −4.7[b] −4.1[b] −5[f] −22.0[b] −21.5[b] −4.6[d]
ΔhydcP [g] −14.1[h] 1.4[h] −2.2[h] 186.7[h] 192.0[h] 52.0[d]

[a] Values in kcal mol−1. [b] From Ref. 126. [c] From Ref. 127. [d] From Ref. 105. [e] Calculated according to ΔH hydG hyd+TΔS hyd. [f] From Ref. 128. [g] Heat capacities in cal K−1 mol−1. [h] From Ref. 129.