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A) Ionic versus radical reactivity for the functionalization of C(sp3)−H bonds. B) γ‐Fluorination and chlorination of tertiary centers by 1,5‐HAT of iminyl radicals. C) γ‐ and δ‐Functionalizations by 1,5‐HAT of amidyl radicals. DG=directing group, FG=functional group, NCS=N‐chlorosuccinimide.
