Table 2.
Comp. | Mobile Phase MeOH/Water (v/v) | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
80:20 | 85:15 | 90:10 | 95:5 | Pure MeOH | ||||||
tr (min) | log k | tr (min) | log k | tr (min) | log k | tr (min) | log k | tr (min) | log k | |
1a | 13.883 | 0.7165 | 10.694 | 0.5756 | 7.830 | 0.3958 | 5.766 | 0.2008 | 4.224 | −0.0403 |
1b | 17.200 | 0.8254 | 12.647 | 0.6656 | 9.449 | 0.5064 | 6.514 | 0.2841 | 4.526 | 0.0203 |
1c | 25.694 | 1.0206 | 16.950 | 0.8162 | 11.292 | 0.6053 | 7.431 | 0.3683 | 5.246 | 0.1287 |
1d | 31.000 | 1.1092 | 19.600 | 0.8882 | 13.553 | 0.7022 | 7.892 | 0.4052 | 5.385 | 0.1573 |
1e | 10.330 | 0.5584 | 6.917 | 0.3183 | 5.400 | 0.1478 | 3.822 | −0.1454 | 3.329 | −0.2956 |
1f | 12.400 | 0.6574 | 9.200 | 0.4911 | 6.280 | 0.2546 | 4.022 | −0.0941 | 3.340 | −0.2913 |
1g | 17.200 | 0.8254 | 11.402 | 0.6104 | 7.483 | 0.3679 | 5.153 | 0.1182 | 3.583 | −0.2067 |
1h | 22.003 | 0.9521 | 13.701 | 0.7159 | 8.532 | 0.4565 | 5.788 | 0.2092 | 3.556 | −0.2153 |
1i | 24.020 | 0.9881 | 16.917 | 0.8153 | 11.691 | 0.6240 | 7.765 | 0.3954 | 5.127 | 0.1205 |
1j | 29.525 | 1.0863 | 20.021 | 0.8981 | 13.060 | 0.6828 | 8.520 | 0.4509 | 5.295 | 0.1449 |
1k | 47.108 | 1.3023 | 27.001 | 1.0424 | 16.533 | 0.8038 | 9.641 | 0.5221 | 6.938 | 0.3303 |
1l | 70.012 | 1.4831 | 38.800 | 1.2152 | 22.636 | 0.9619 | 11.670 | 0.6271 | 7.756 | 0.3996 |
1m | 15.731 | 0.7805 | 9.218 | 0.4922 | 6.420 | 0.2695 | 4.685 | 0.0424 | 3.519 | −0.2275 |
1n | 22.183 | 0.9502 | 12.370 | 0.6542 | 8.156 | 0.4205 | 4.995 | 0.0941 | 3.947 | −0.1047 |
1o | 29.174 | 1.0807 | 13.651 | 0.7059 | 9.634 | 0.5174 | 5.095 | 0.1095 | 4.127 | −0.0618 |
1p | 33.719 | 1.1484 | 17.129 | 0.8215 | 11.332 | 0.6072 | 5.801 | 0.2051 | 3.925 | −0.1102 |