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. 2018 Sep 12;23(9):2333. doi: 10.3390/molecules23092333

Table 2.

Tigliane type diterpenoids from the genus Croton.

No. Compound Name Molecular Formula Sources Ref
93 12-O-isobutyrylphorbol-13-decanoate C34H52O8 C. tiglium [45]
94 12-O-(2-methyl)butyrylphorbol-13-octanoate C33H50O8 C. tiglium [45]
95 12-O-[(2R)-N,N-dimethyl-3-methylbutanoyl]-4-deoxyphorbol 13-acetate C29H43NO7 C. ciliatoglandulifer [41]
96 12-O-[(2S)-N,N-dimethyl-3-methylbutanoyl]-4-deoxyphorbol 13-acetate C29H43NO7 C. ciliatoglandulifer [41]
97 12-O-[(2R)-N,N-Dimethyl-3-methylbutanoyl]phorbol 13-acetate C29H43NO8 C. ciliatoglandulifer [41]
98 12-O-[3-Methyl-2-butenoyl]-4-deoxyphorbol 13-acetate C27H36NO7 C. ciliatoglandulifer [41]
99 12-O-(2-methyl)butyrylphorbol-13-tiglate C30H42O8 C. tiglium [46]
100 12-O-tiglylphorbol-13-propionate C28H38O8 C. tiglium [46]
101 13-O-acetylphorbol-20-oleate C40H62O8 C. tiglium [46]
106 12-O-tiglyl-4-deoxy-4α-phorbol-13-(2-methyl)butyrate C30H42O7 C. tiglium [46]
107 Alienusolin C42H66O8 C. alienus [42]
108 12-O-acetyl-5,6-didehydro-7-oxophorbol-13-yl 2-methylbutanoate C27H36O9 C. tiglium [47]
109 12-O-acetyl-5,6-didehydro-7-oxophorbol-13-yl2-methylpropanoate C26H34O9 C. tiglium [47]
110 12-Oacetyl-5,6-didehydro-6,7-dihydro-7-hydroxyphorbol-13-yl 2-methylbutanoate C27H38O9 C. tiglium [47]
111 12-O-decanoyl-7-hydroperoxy-phorbol-5-ene-13-acetate C32H42O10 C. mauritianus [43]
112 20-deoxy-20-oxophorbol12-tiglate 13-(2-methyl)butyrate C30H40O8 C. tiglium [48]
113 12-O-acetylphorbol-13-isobutyrate C26H36O8 C. tiglium [48]
114 12-O-benzoylphorbol-13-(2-methyl)butyrate C32H40O8 C. tiglium [48]
115 12-O-tiglyl-7-oxo-5-ene-phorbol-13-(2-methyl)butyrate C30H40O9 C. tiglium [48]
116 13-O-(2-metyl)butyryl-4-deoxy-4a-phorbol C25H36O6 C. tiglium [48]
117 Crotignoid A C30H42O10 C. tiglium [49]
118 Crotignoid B C29H40O10 C. tiglium [49]
119 Crotignoid C C30H42O9 C. tiglium [49]
120 Crotignoid D C29H40O9 C. tiglium [49]
121 Crotignoid E C29H38O9 C. tiglium [49]
122 Crotignoid F C28H36O9 C. tiglium [49]
123 Crotignoid G C30H44O8 C. tiglium [49]
124 Crotignoid H C29H38O8 C. tiglium [49]
125 Crotignoid I C30H44O8 C. tiglium [49]
126 Crotignoid J C31H38O8 C. tiglium [49]
127 Crotignoid K C29H34O7 C. tiglium [49]
128 Crotusin A C36H54O10 C. caudatus [44]
129 Crotusin B C46H72O11 C. caudatus [44]
130 Crotusin C C36H52O11 C. caudatus [44]
131 12-O-tiglylphorbol-4-deoxy- 4β-phorbol-13-acetate C27H36O7 C. tiglium [50]
132 12-O-tiglylphorbol-4-deoxy-4β-phorbol-13-hexadecanoate C41H64O7 C. tiglium [50]
133 13-O-acetylphorbol-4-deoxy-4β-phorbol-20-oleate C40H62O7 C. tiglium [50]
134 13-O-acetylphorbol-4-deoxy-4β-phorbol-20-linoleate C40H60O7 C. tiglium [50]
135 4-deoxy-20-oxophorbol 12-tiglyl 13-acetate C27H34O7 C. tiglium [51]
136 7-oxo-5-ene-phorbol-13-(2-methylbutyrate) C25H34O8 C. tiglium [51]
137 7-hydroxyl-phorbol-5-ene-13-(2-methyl)butyrate C25H36O8 C. tiglium [51]