Table 4.

(a) List of diagnostic ions for H. itama honey based on UHPLC-QTOF mass spectrometric data. (b) List of diagnostic ions for G. thoracica honey based on UHPLC-QTOF mass spectrometric data. (c) List of diagnostic ions for T. apicalis honey based on UHPLC-QTOF mass spectrometric data.

(a)
VIP > 1	Var ID (Primary)	Ion	RT (min)	Experimental Precursor Ions (m/z)	Experimental MS-MS Fragment Ions (m/z)
1.66	492	[M + H]+	1.44	193.087	165.092, 162.068, 147.044, 135.044, 133.065, 105.071
1.62	493	[M + H]+	1.50	151.076
1.91	428	[M + H]+	1.55	446.203
1.66	399	[M + H]+	1.55	105.070
1.83	359	[M + H]+	1.56	122.096	106.073, 105.070, 103.054
1.79	396	[M + H]+	1.57	266.139
1.78	397	[M + H]+	1.57	284.150	268.145, 267.143, 266.139, 249.132, 248.129, 164.107, 134.097, 105.070
1.77	451	[M + H]+	1.57	267.142
1.72	431	[M + H]+	1.80	392.133
1.71	401	[M + H]+	1.80	225.110	181.084, 165.055, 139.076, 121.065
1.15	490	[M + H]+	1.80	234.150	191.105, 189.091, 122.032, 121.029, 114.128
1.08	276	[M + H]+	3.03	362.327
1.07	120	[M + H]+	4.94	310.311
1.03	188	[M + H]+	4.95	695.361
1.08	226	[M + H]+	5.04	637.307
1.03	216	[M + H]+	5.04	695.360	659.294, 581.245, 359.032, 330.992, 289.006, 135.004
1.47	416	[M + H]+	5.13	358.309	178.945, 177.013, 136.006, 135.003, 132.987, 123.117, 120.987, 105.068, 104.992
1.22	418	[M + H]+	5.13	336.327
1.05	470	[M + H]+	5.27	371.102
1.57	19	[M + H]+	5.54	360.324	358.365, 135.004
1.56	124	[M + H]+	5.54	321.316
1.55	8	[M + H]+	5.54	338.343
1.52	107	[M + H]+	5.54	675.678	338.343, 321.316, 303.305, 149.133, 135.117, 111.117, 97.102
1.05	444	[M + H]+	6.07	679.366
1.45	410	[M + H]+	6.09	366.374
1.15	78	[M − H]-	1.00	668.224
1.17	50	[M − H]-	1.69	495.183
1.63	60	[M − H]-	1.73	493.168
1.57	39	[M − H]-	1.82	119.114
1.66	42	[M − H]-	1.83	353.112	227.051, 211.030, 190.984, 166.013, 165.009, 147.014, 120.048, 119.046
1.27	31	[M − H]-	1.83	147.098
1.16	29	[M − H]-	1.83	165.102
1.41	46	[M − H]-	1.86	206.118
1.15	45	[M − H]-	2.37	201.075
(b)
VIP > 1	Var ID (Primary)	Ion	RT (min)	Experimental Precursor Ions (m/z)	Experimental MS-MS Fragment Ions (m/z)
1.62	126	[M + H]+	1.03	365.106
1.32	475	[M + H]+	1.13	174.149
1.32	283	[M + H]+	1.30	365.106
1.44	301	[M + H]+	1.41	203.053
1.33	348	[M + H]+	1.69	365.106
1.44	521	[M + H]+	1.81	351.142
1.46	502	[M + H]+	1.82	317.114
1.46	502	[M + H]+	1.82	317.114
1.33	501	[M + H]+	1.97	227.083	210.074, 209.071, 199.087, 181.076, 154.065
1.36	517	[M + H]+	1.99	521.272	519.256, 518.236, 517.228, 366.109, 365.106, 285.887, 218.941, 203.050, 185.042, 140.070, 135.004, 132.985
1.46	528	[M + H]+	2.01	301.118
1.46	528	[M + H]+	2.01	301.118
1.46	528	[M + H]+	2.01	301.118
1.46	528	[M + H]+	2.01	301.118
1.27	479	[M + H]+	2.05	321.131	319.210, 319.161, 281.016, 279.020, 187.060, 142.948
1.30	388	[M + H]+	2.08	183.091	182.154, 155.047, 127.016, 98.984
1.35	516	[M + H]+	2.11	551.283
1.41	483	[M + H]+	4.91	439.375
1.43	421	[M + H]+	5.27	367.319
1.51	503	[M + H]+	5.35	393.334
1.80	478	[M + H]+	5.49	467.408
1.25	520	[M + H]+	5.73	481.387
1.00	486	[M + H]+	5.78	637.469
1.46	519	[M + H]+	5.87	391.320
1.68	87	[M − H]-	4.86	345.255
1.80	86	[M − H]-	5.42	373.283
1.83	88	[M − H]-	5.93	401.311
(c)
VIP > 1	Var ID (Primary)	Ion	RT (min)	Experimental Precursor Ions (m/z)	Experimental MS-MS Fragment Ions (m/z)
1.07	364	[M + H]+	1.45	492.207	408.165, 332.243, 292.119, 264.124, 244.097, 166.086, 121.084, 120.081
1.13	183	[M + H]+	1.61	158.082
1.12	245	[M + H]+	1.62	178.086
1.22	110	[M + H]+	1.64	389.178
1.23	171	[M + H]+	1.67	515.173
1.26	250	[M + H]+	1.68	238.108
1.11	208	[M + H]+	1.68	535.236
1.27	362	[M + H]+	1.69	311.113
1.27	111	[M + H]+	1.69	227.126
1.30	140	[M + H]+	1.70	353.121
1.19	146	[M + H]+	1.71	373.183
1.21	119	[M + H]+	1.73	211.131
1.14	137	[M + H]+	1.83	260.090
1.04	191	[M + H]+	1.83	401.171
1.02	373	[M + H]+	1.78	107.085
1.00	365	[M + H]+	1.80	180.102
1.07	369	[M + H]+	1.81	151.112
1.19	85	[M + H]+	1.84	120.081
1.15	142	[M + H]+	1.85	649.269
1.30	141	[M + H]+	1.86	192.103
1.02	195	[M + H]+	1.86	230.080
1.17	215	[M + H]+	1.93	162.091
1.09	381	[M + H]+	1.95	644.313
1.17	382	[M + H]+	1.96	283.152
1.17	382	[M + H]+	1.96	283.152
1.15	246	[M + H]+	1.96	153.127
1.15	246	[M + H]+	1.96	153.127
1.28	17	[M + H]+	2.00	487.215
1.26	69	[M + H]+	2.00	482.260	355.174, 335.095, 154.131, 153.128, 135.117, 115.039, 97.028
1.08	249	[M + H]+	2.00	171.138
1.13	112	[M + H]+	2.02	153.127
1.04	42	[M + H]+	2.04	355.173
1.01	368	[M + H]+	2.14	253.142
1.39	175	[M + H]+	2.23	293.173
1.14	394	[M + H]+	2.26	307.152
1.00	372	[M + H]+	2.26	267.158
1.34	392	[M + H]+	2.30	195.138
1.34	392	[M + H]+	2.30	195.138
1.37	383	[M + H]+	2.33	249.146
1.32	391	[M + H]+	2.38	253.179
1.27	237	[M + H]+	2.38	291.157
1.38	200	[M + H]+	2.41	439.230
1.30	377	[M + H]+	2.42	221.154
1.44	393	[M + H]+	2.44	217.159
1.34	189	[M + H]+	2.45	235.170
1.37	193	[M + H]+	2.47	423.235
1.06	253	[M + H]+	2.47	251.165
1.36	201	[M + H]+	2.48	275.162
1.02	260	[M + H]+	2.49	233.154
1.00	232	[M + H]+	2.52	421.219
1.45	65	[M + H]+	2.61	277.178
1.11	154	[M + H]+	2.63	223.169
1.42	95	[M + H]+	2.73	219.175
1.06	248	[M + H]+	2.76	237.185
1.09	255	[M + H]+	2.77	261.183
1.40	92	[M + H]+	2.89	511.340
1.11	330	[M + H]+	3.05	272.259
1.17	412	[M + H]+	3.67	359.030
1.26	93	[M + H]+	3.73	359.030
1.09	75	[M + H]+	4.06	711.131
1.00	367	[M + H]+	4.95	359.030	358.368, 358.309, 342.310, 341.307, 285.279, 267.271, 136.007, 135.003, 123.117, 109.102
1.07	194	[M + H]+	5.00	359.030
1.04	61	[M + H]+	5.45	983.202
-	-	[M − H]-	-	-	-