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. 2018 Sep 2;23(9):2230. doi: 10.3390/molecules23092230

Table 1.

Thermodynamic and kinetic parameters of the activation energy and entropy associated to the transesterification reaction yield for free and immobilized CAL-B.

Biocatalyst Ea (kJ mol−1) ΔS (J mol−1) k (μMs−1) a Yield (%) b
Free CAL-B 29.4 −73 0.048 2/1.5 c
NP-ImS4/CAL-B 25.6 −138 33.2 79.7
NP-ImS10/CAL-B 18.2 −142 21.7 90
NP-ImS18/CAL-B 27.8 −145 14.0 83

a- Determined at 32 °C; b- determined at at 32 °C and 24 hours.; c- reaction in presence of ImS10 surfactant.