Table 1.
Biocatalyst | Ea (kJ mol−1) | ΔS ≠ (J mol−1) | k (μMs−1) a | Yield (%) b |
---|---|---|---|---|
Free CAL-B | 29.4 | −73 | 0.048 | 2/1.5 c |
NP-ImS4/CAL-B | 25.6 | −138 | 33.2 | 79.7 |
NP-ImS10/CAL-B | 18.2 | −142 | 21.7 | 90 |
NP-ImS18/CAL-B | 27.8 | −145 | 14.0 | 83 |
a- Determined at 32 °C; b- determined at at 32 °C and 24 hours.; c- reaction in presence of ImS10 surfactant.