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. Author manuscript; available in PMC: 2019 Apr 1.
Published in final edited form as: Appl Radiat Isot. 2017 Jul 27;134:23–31. doi: 10.1016/j.apradiso.2017.07.050

Table 2.

Th Mass spectrometry analysis information.

Laboratory LANL LLNL IPGP-CEA
Instrument ThermoFisher Neptune
MC-ICP-MS
Nu-Plasma HR
MC-ICP-MS
ThermoFisher Neptune
MC-ICP-MS (at IPGP)
Collectors 9 Faraday,
7 Channeltron,
1 SEM w/ RPQ
5 Faraday,

3 SEMs (2 w/ RPQ)
9 Faraday,

1 SEM w/RPQ
Introduction System Stable Signal Spray Chamber Cetac Aridus II APEX HF (ESI)
Nebulizer PFA-FTST Element Scientific Cetac PFA Nebulizer PFA Micro-flow Nebulizer
Nebulizer Gas Flow 0.9 L/min 0.94 L/min Not Reported
Solution Uptake 250 µL/min 120 µL/min 50 µL/min
Mass Bias CRM CRM U010 (NBL, 2008a) CRM U010 (NBL, 2008a) CRM U500 (NBL, 2008b)
Quality Control CRM IRMM-035 (IRMM, 1997)
CRM 112A (NBL, 2010)
CRM U005A (NBL, 2008c) CRM U100 (NBL, 2008d)
Corrections Applied Detector Baseline
Instrument Background
Peak Tailing
Detector Gains
Mass Bias
Hydride Correction
Detector Baseline

Instrument Background
Peak Tailing
Detector Gains
Mass Bias
Detector Baseline
Instrument Background
Peak Tailing
Detector Gains
Mass Bias
Hydride Correction

Summary of instrumental parameters and analysis conditions for thorium isotopic ratio measurements. MC-ICP-MS is Multi-Collector Inductively Coupled Plasma Mass Spectrometry.