Table 3.
Sample number | Analysis lab | Measured 229Th Molality (mol g−1) | Ampoule number | IDMS spike |
---|---|---|---|---|
21R | LANL | (1.1485 ± 0.0023) × 10−10 | 151 | Dilution 2 |
22R | LLNL | (1.1498 ± 0.0024) × 10−10 | Dilution 2 | |
26R | LANL | (1.1489 ± 0.0018) × 10−10 | 126 | Dilution 2 |
27R | LLNL | (1.1500 ± 0.0031) × 10−10 | Dilution 2 | |
34R | CEA | (1.1486 ± 0.0021) × 10−10 | Dilution 2 | |
39R | LANL | (1.1493 ± 0.0021) × 10−10 | 72 | Dilution 2 |
41R | LLNL | (1.1499 ± 0.0027) × 10−10 | 173 | Dilution 2 |
43R | LANL | (1.1492 ± 0.0026) × 10−10 | 49 | Dilution 2 |
44R | LLNL | (1.1494 ± 0.0037) × 10−10 | 67 | Dilution 2 |
45R | LANL | (1.1490 ± 0.0017) × 10−10 | Dilution 2 | |
46R | LLNL | (1.1498 ± 0.0021) × 10−10 | 176 | Dilution 2 |
2R | CEA | (1.1491 ± 0.0024) × 10−10 | 41 | Dilution 2 |
5R | CEA | (1.1486 ± 0.0021) × 10−10 | 4 | Dilution 2 |
10R | CEA | (1.1482 ± 0.0021) × 10−10 | 82 | Dilution 2 |
A2 | LLNL | (1.1497 ± 0.0019) × 10−10 | 17–06-1 | Dilution 2A |
A3 | LANL | (1.1476 ± 0.0035) × 10−10 | Dilution 2A | |
A4 | LANL | (1.1511 ± 0.0029) × 10−10 | 17–06-2 | Dilution 2A |
B4 | LLNL | (1.1506 ± 0.0018) × 10−10 | Dilution 2B | |
B2 | LLNL | (1.1503 ± 0.0019) × 10−10 | 18–02-1 | Dilution 2B |
B3 | LANL | (1.1507 ± 0.0029) × 10−10 | Dilution 2B | |
32R | LANL | (1.152 ± 0.010) × 10−10 | 96 | SRM 4342A |
33R | LLNL | (1.156 ± 0.010) × 10−10 | SRM 4342A | |
40R | CEA | (1.157 ± 0.010) × 10−10 | SRM 4342A | |
229Th Half-life Reference | Activity Based 229Th Molality (mol g−1) | 229Th Half-life Value (years) | ||
Goldstein et al. (1989) | (1.158 ± 0.019) × 10−10 | 7880 ± 120 | ||
“A” Varga et al. (2014) | (1.160 ± 0.011) × 10−10 | 7889 ± 64 | ||
“B” Varga et al. (2014) | (1.169 ± 0.012) × 10−10 | 7952 ± 72 | ||
Kinkunaga et al., 2011 | (1.166 ± 0.010) × 10−10 | 7932 ± 55 |
Summary of measured 229Th molality values for the reference material. Uncertainties are expanded uncertainties (U = k uc) with a coverage factor (k) of approximately 2. Reference material samples that were spiked with Dilution 2 and SRM 4342A were prepared and analyzed in 2012. Ampoule numbers associated with these samples represent filling order number. The samples spiked with Dilutions 2A and 2B were prepared and analyzed in 2015. Ampoule numbers for the later analyses represent unit identification numbers. Activity based molality values for the 229Th reference material were calculated using half-lives from cited publications and assuming a massic activity of (194.4 ± 1.1) Bq g−1. Half-lives for the italicized data were determined using methods that are dependent on half-live values of other isotopes. Half-lives for un-italicized values are based on direct thorium amount-versus-activity measurements.