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. Author manuscript; available in PMC: 2019 Apr 1.
Published in final edited form as: Appl Radiat Isot. 2017 Jul 27;134:23–31. doi: 10.1016/j.apradiso.2017.07.050

Table 4.

229Th Reference Material Attribute Uncertainty Budgets.

Components Comment Type ui%
n (230Th)/n (229Th) Isotope Amount Ratio
Measured n(230Th)/n
  (229Th)
Standard uncertainty of measurement
data
A 2.4
Calibration CRM(s) Standard uncertainty of calibration CRMs
for MC-ICP-MS measurements
B 0.041
Detector Yield
  Calibration
Uncertainty for SEM-Faraday collector
inter-calibration
B 0.50
Th Blank Correction Reagent and instrument blank
uncertainty
B 0.085
229Th Hydride
  Correction
229ThH+ correction uncertainty B 0.097
Relative combined standard uncertainty (uc) 2.5
n(230Th)/n(229Th)         Expanded Uncertainty (k = 2)
5.18 × 10−5         0.26 × 10−5 (Relative: 5.0%)
n(232Th)/n(229Th) Isotope Amount Ratio
Measured n(232Th)/n
  (229Th)
Standard uncertainty of measurement
data
A 1.1
Calibration CRM(s) Standard uncertainty of calibration CRMs
for MC-ICP-MS measurements
B 0.041
Detector Yield
  Calibration
Uncertainty for SEM-Faraday collector
inter-calibration
B 0.50
Th Blank Correction Reagent and instrument blank
uncertainty
B 0.12
Relative combined standard uncertainty (uc) 1.2
n(232Th)/n(229Th)         Expanded Uncertainty (k = 2)
3.815 × 10−4         0.092 × 10−4 (Relative: 2.4%)
229Th Molality
Measured 229Th
  Molality
Standard uncertainty of measurement
data
A 0.043
Molality 232Th Spikes Standard uncertainties of IDMS spikes B 0.015
Calibration CRM(s) Standard uncertainties of calibration
CRMs for MC-ICP-MS measurements
B 0.042
Mass Bias Correction Uncertainty for use of uranium CRM for
thorium mass bias correction
B 0.025
Aliquot Weighing Uncertainty for potential evaporation
during sample weighing.
B 0.015
Relative combined standard uncertainty (uc) 0.068
229Th Molality (mol g−1)         Expanded Uncertainty (k = 2)
1.1498 × 10−10         0.0016 × 10−10 (Relative: 0.14%)

Uncertainty budgets for the 229Th reference material attributes. Values are shown for a reference date of 15 September 2012. Only the most significant uncertainty components are shown.