Table 4.
Components | Comment | Type | ui% |
---|---|---|---|
n (230Th)/n (229Th) Isotope Amount Ratio | |||
Measured n(230Th)/n (229Th) |
Standard uncertainty of measurement data |
A | 2.4 |
Calibration CRM(s) | Standard uncertainty of calibration CRMs for MC-ICP-MS measurements |
B | 0.041 |
Detector Yield Calibration |
Uncertainty for SEM-Faraday collector inter-calibration |
B | 0.50 |
Th Blank Correction | Reagent and instrument blank uncertainty |
B | 0.085 |
229Th Hydride Correction |
229ThH+ correction uncertainty | B | 0.097 |
Relative combined standard uncertainty (uc) | 2.5 | ||
n(230Th)/n(229Th) | Expanded Uncertainty (k = 2) | ||
5.18 × 10−5 | 0.26 × 10−5 (Relative: 5.0%) | ||
n(232Th)/n(229Th) Isotope Amount Ratio | |||
Measured n(232Th)/n (229Th) |
Standard uncertainty of measurement data |
A | 1.1 |
Calibration CRM(s) | Standard uncertainty of calibration CRMs for MC-ICP-MS measurements |
B | 0.041 |
Detector Yield Calibration |
Uncertainty for SEM-Faraday collector inter-calibration |
B | 0.50 |
Th Blank Correction | Reagent and instrument blank uncertainty |
B | 0.12 |
Relative combined standard uncertainty (uc) | 1.2 | ||
n(232Th)/n(229Th) | Expanded Uncertainty (k = 2) | ||
3.815 × 10−4 | 0.092 × 10−4 (Relative: 2.4%) | ||
229Th Molality | |||
Measured 229Th Molality |
Standard uncertainty of measurement data |
A | 0.043 |
Molality 232Th Spikes | Standard uncertainties of IDMS spikes | B | 0.015 |
Calibration CRM(s) | Standard uncertainties of calibration CRMs for MC-ICP-MS measurements |
B | 0.042 |
Mass Bias Correction | Uncertainty for use of uranium CRM for thorium mass bias correction |
B | 0.025 |
Aliquot Weighing | Uncertainty for potential evaporation during sample weighing. |
B | 0.015 |
Relative combined standard uncertainty (uc) | 0.068 | ||
229Th Molality (mol g−1) | Expanded Uncertainty (k = 2) | ||
1.1498 × 10−10 | 0.0016 × 10−10 (Relative: 0.14%) |
Uncertainty budgets for the 229Th reference material attributes. Values are shown for a reference date of 15 September 2012. Only the most significant uncertainty components are shown.