(1): Cholesta-1,4,22-trien-3-one; (2): (22E)-19-Norcholesta-1,3,5(10),22-tetraen-3-ol; (3): 24-Methylenecholesta-1,4,22-trien-3-one; (4): 24-Methylene-19-norcholesta-1,3,5(10),22-tetraen-3-ol. Paraestrol A (19-norcholesta-1,3,5(10)-trien-3-ol) has been proposed as an ancestral steroid [28]. We have named « dienone aromatization » the proposed aromatization reaction to stress the difference from the vertebrate case where there is no delta1–2 double bond (highlighted in yellow) on the A ring.