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. 2008 Oct 16;13(10):2521–2544. doi: 10.3390/molecules13102521

Table 1.

Recent publications on LC-MS analysis of flavonoids in plants.

Method Eluents (v/v) Sample Flavonoids Reference
CEC–UV 337nm pH 2.8 phosphate buffer at 50 mmol L−1 containing 50% acetonitrile Chamomilla recutita 11 phenolic compounds including 7 flavonoids [55]
MEKC–UV
275nm
15 mM borate, 30mM sodium dodecyl sulfate (SDS) and 10% (v/v) ethanol at pH 10.5 Ixeridium gracile Luteolin 7-O-glucoside, 2′,4′-dihydroxydihydrochalcone, 2′,4′-dihydroxychalcone, 7-hydroxyflavanone and quercetin 3-O-galactoside [56]
MEKC–UV
214nm
Borate buffer containing SDS at pH 9.0 Various types of wines. Catechin, naringenin, quercetin,
apigenin, kaempferol and myricetin
[57]
MEKC–UV
254nm
50mM borax, 25mM sodium dodecyl sulfate and 30% of acetonitrile(pH 6.75) Arnica montana L. 7 flavonoids and 4 caffeic acid derivatives [58]
CE–ED Borate buffer (pH 9.0) grapefruit peel and juice Hesperidin, naringin, hesperedin, narigenin and rutin and ascorbic acid [59]
CZE-AD β-CD and the mixture of methanol and ethanol as modifiers Chrysanthemum Apigenin, luteolin, kaempferol, quercetin, (+)-catechin and (−)-epicatechin [60]
CZE–UV 270nm 50mM borate buffer (pH 10.0) Epimedium Icariin, epimedin A, epimedin B and epimedin C [61]
CE–UV 210nm pH 9.0 with 30mM borate as buffer containing 8% (v/v) acetonitrile Lamiophlomis rotata Luteolin-7-O-glucoside, isorhamnetin,
apigenin, luteolin and quercetin
[62]
CEC–UV 260nm 10 mM ammonium formate, pH 3.0. Adinandra nitida Epicatechin, camellianin A, rhoifolin camellianin B, apigenin. [63]