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. Author manuscript; available in PMC: 2019 Feb 23.
Published in final edited form as: J Nat Prod. 2018 Feb 1;81(2):316–322. doi: 10.1021/acs.jnatprod.7b00745

Figure 2.

Figure 2.

C−S bond-forming TSs in the asymmetric SMA reactions of MeS− to PTM and PTN mimics. M06–2X/6–31+G(d,p)/CPCM (dichloromethane) was used. All energies are in kcal mol−1 and bond distances in Å.