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. Author manuscript; available in PMC: 2019 Sep 12.
Published in final edited form as: J Am Chem Soc. 2018 Jul 26;140(36):11317–11324. doi: 10.1021/jacs.8b05868

Table 5.

Aryl Halide Scope

graphic file with name nihms-987197-t0012.jpg

A) Aryl halide scope for sec-alkyl conditions starting from olefin 6a.

a

0.3 mmol scale, isolated yield, reaction time: 12—48 h. 1 mL 1,4-dioxane, N2 atmosphere for 2 h, then open to air. All substrates gave >20:1 branched:linear ratio except where notated

b

2:1 ratio of arylation at C3 vs C2.

(B) Aryl halide scope for tert-alkyl conditions using olefin 21a.

c

0.3 mmol scale, isolated yield, reaction time 16 h. 1.5 mL 1,2-DCE and 1.5 mL NMP. N2 atmosphere for 1.5 h then open to air.