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. Author manuscript; available in PMC: 2019 Nov 21.
Published in final edited form as: J Phys Chem A. 2018 Nov 9;122(46):9107–9114. doi: 10.1021/acs.jpca.8b07163

Figure 4.

Figure 4.

Experimentally measured SLIC-SABRE{1H} (blue squares) and SLIC/dc-SABRE{1H} (green circles) signal amplitudes as a function of temperature and effective dissociation constant rate, kd'. Corresponding quantitative SABRE theory simulations (solid lines) for a [IrH2S2] complex with S=15N. To interrelate temperature and dissociation rate, Eyring equation with entropy ΔS = 52.9 J/mol·K and enthalpy ΔH = 79.4 kJ/mol of activation was used.