Table 1.

NMR data for the S-layer polysaccharide PS-B (ppm from acetone, 600 MHz, 35 °C)

	H/C-1	H/C-2	H/C-3	H/C-4	H/C-5	H/C-6
Ribf A	5.31	4.14	3.99	4.35	3.70; 3.76
	99.0	72.5	71.1	86.4	62.6
Ribf A′	5.26	4.11	3.97	4.46	3.74; 3.74
	99.4	72.6	71.5	86.5	62.6
Ribf A″	5.30	4.14	3.99	4.35	3.70; 3.76
	99.0	72.5	71.1	86.4	62.6
α-Glc B	5.10	3.59	3.93	3.68	4.01	3.80; 3.89
	96.5	72.5	73.9	77.9	71.6	61.6
α-Rha C	5.06	4.14	3.96	3.62	3.95	1.32
	103.3	71.2	70.2	83.8	68.7	17.9
α-Rha D	5.04	4.15	3.92	3.56	3.86	1.31
	103.3	71.2	79.7	72.5	70.5	17.9
α-Rha E	5.03	4.17	3.91	3.58	3.88	1.30
	103.3	71.2	79.4	72.5	70.4	17.9
β-Rha F	4.90	4.15	3.72	3.54	3.54	1.34
	101.9	71.2	72.7	83.7	72.1	17.9
β-Rha K	4.97	4.68	4.34	3.62	3.45	1.33
	99.6	75.8	81.1	74.1	72.3	17.9
β-Rha L	4.77	4.24	3.68	3.44	3.43	1.34
	101.0	68.1	78.9	73.5	73.6	17.9
β-Rha M	4.76	4.34	3.94	3.74	3.62	1.38
	101.4	68.1	75.5	77.8	72.9	18.2
β-Rha M′	4.78	4.33	3.90	3.80	3.62	1.40
	101.4	68.4	75.5	78.2	72.9	18.2
β-Rha M″	4.77	4.34	3.94	3.74	3.62	1.38
	101.4	68.1	75.5	77.8	72.9	18.2
β-Gal N	4.56	3.65	3.72	4.03	3.73	3.78; 3.78
	102.0	71.3	81.3	69.6	76.3	62.1
Thr*		4.60	4.34	1.29
		59.5	75.3	17.0
Thr		4.00	4.22	1.34
		59.7	67.3	19.9
Gly		3.98; 3.98
		43.8
Ala		4.20	1.33
		52.0	18.8