Table 3.
Complex | Step | Thermal effect | Temperature range/°C | Δmexp/% | Δmcalcd/% | ||||
---|---|---|---|---|---|---|---|---|---|
[VO(rutin)(H2O)2](SO4)0.5 2H2O | 1 | Endothermic | 78–140 | 9.04 | 9.04 | ||||
2 | Exothermic | 140–388 | 40.52 | 40.66 | |||||
3 | Exothermic | 388–812 | 33.94 | 33.88 | |||||
4 | Exothermic | 812–900 | 4.98 | 5.02 | |||||
[VO(Rut)2] 4H2O | 1 | Endothermic | 55–94 | 5.38 | 5.31 | ||||
2 | Exothermic | 94–362 | 47.68 | 47.75 | |||||
3 | Exothermic | 362–900 | 40.87 | 40.83 |