Table 2.
Position | 1 | 2 | |||
---|---|---|---|---|---|
δH | δC | δH | δC | ||
1a | 1.39 (m) | 32.1 | 38.5 | ||
1b | 167 (m) | ||||
2 | 1.49 (m) | 27.5 | 2.24 ddd (14.3, 14, 6.4) | 35.1 | |
1.85 (m) | 2.75 ddd (14.3, 3.6, 3.4) | ||||
3 | 4.68 (s br) | 78.3 | 216.8; 216.7 | ||
4 | 36.9 | 47.9 | |||
5 | 1.79 (m) | 46.1 | 1.82 (m) | 52.5; 52.4 | |
6 | 1.73 (m) | 22.9 | 1.70 (m) | 23.3 | |
7 | 5.23 (d, 2.4) | 118.2; 118.1 | 5.28 br | 118.2; 118.1 | |
8 | 146.0; 145.9 | 145.8; 145.6 | |||
9 | 2.30 (t, 7.6); 2.2 (t, 7.6) | 49.7; 48.8 | 49.6; 48.4 | ||
10 | 34.9 | 34.9 | |||
11 | 1.54 (m) | 17.4 | 17.8 | ||
12a | 1.53 (m) | 35.3 | 35.2 | ||
12b | 1.98 (m) | ||||
13 | 43.8; 43.6 | 43.8; 43.6 | |||
4 | 50.9; 50.4 | 50.8; 50.5 | |||
15 | 1.55 (m) | 34.2 | 34.3 | ||
16 | 1.61 (m) | 27.5; 27.1 | 27.5; 27.3 | ||
17 | 2.01 (m); 2.04 (m) | 47.1; 45.2 | 2.03 (m); 2.06 (m) | 47.1; 45.2 | |
18 | 0.90 (s) | 23.9 | 0.80 (s); 085 (s) | 24.6 | |
19 | 0.76 (s) | 13.0 | 12.8 | ||
20 | 1.71 (m) | 33.8; 31.7 | 33.8; 31.7 | ||
21 | 5.33 (d, 2.8); 5.29 (d,2.8) | 101.8; 97.8 | 101.8; 97.8 | ||
22 | 1.98 (m) | 31.5; 31.3 | 31.5; 31.3 | ||
23 | 3.89 (m); 3.83 (m) | 78.5; 77.0 | 3.88 (m); 3.84 (m) | 78.5; 77.1 | |
24 | 2.82 (d, 7.6); 2.67(d,7.6) | 67.8; 65.3 | 2.81 (d, 7.6); 2.67 (d, 7.6) | 67.8; 65.4 | |
25 | 58.0; 57.2 | 58.0; 57.2 | |||
26a) | 1.29 (s); 1.28 (s) | 25.0; 24.9 | 1.29(s); 1.28 (s) | 25.0; 24.9 | |
27a) | 1.27 (s) | 19.4; 19.2 | 1.26 (s) | 19.5; 19.2 | |
28 | 0.81 (s) | 27.6 | 0.97 (s) | 24.4 | |
29 | 0.95 (s) | 21.4 | 0.98 (s) | 21.6 | |
30 | 0.98 (s); 0.96 (s) | 22.6; 22.3 | 1.00 (s); 1.07 (s) | 22.6 | |
1′ | 167.5 | ||||
2′ | 129.2 | ||||
3′ | 6.80 (qq, 6.8, 1.6) | 136.6 | |||
4′ | 1.75 (d, 6.8) | 14.4 | |||
5′ | 1.81 (s) | 12.2 |
a) values within any column may be interchanged.