Table 1.
1H- (300 MHz) and 13C- (75.5 MHz) NMR Data of Compounds 1 and 2 in CDCl3.
Position | Compound 1 | Compound 2 | ||||
---|---|---|---|---|---|---|
δH | δC | HMBC | δH | δC | HMBC | |
1 | - | 159.1 | - | - | 154.0 | - |
2 | - | 149.6 | - | - | 152.7 | - |
3 | 7.28, 1H, d, J = 8.7 Hz | 115.9 | C-2, C14 | 7.19, 1H, d, J = 8.4 Hz | 115.6 | C-2, C-14 |
4 | 8.17, 1H, d, J = 8.7 Hz | 125.2 | C-3, C-10,C-13, C-14 | 7.89, 1H, d, J = 8.4 Hz | 121.0 | C-3, C-10, C-13, C-14 |
5 | 8.06, 1H, s | 126.9 | C-7, C-10, C-11 | 8.12, 1H, s | 127.8 | 6-CH3, C-10, C-11 |
6 | - | 144.6 | - | - | 146.2 | - |
7 | 7.58, 1H, dd, Jo = 7.8 Hz, Jm = 1.7 Hz | 134.7 | 6-CH3, C-8, C-12 | 7.61, 1H, d, J = 8.1 Hz | 134.6 | C-6,C-8 |
8 | 8.17, 1H, d, J = 7.8 Hz | 127.0 | C-6, C-9 | 8.23, 1H, d, J = 8.1 Hz | 127.1 | C-7, C-9, C-12 |
9 | - | 182.7 | - | - | 189.1 | - |
10 | - | 182.7 | - | - | 181.8 | - |
11 | - | 132.9 | - | - | 134.0 | - |
12 | - | 132.9 | - | - | 131.1 | - |
13 | - | 127.4 | - | - | 116.1 | - |
14 | - | 127.5 | - | - | 125.5 | - |
1-OH | - | - | - | 13.20,1H,s | - | |
1-OCH3 | 4.02, 3H, s | 61.3 | C-1 | - | - | - |
2-OCH3 | 4.02, 3H, s | 56.3 | C-1,C-2,C-3 | 4.04, 3H, s | 56.4 | C-1,C-3 |
6-CH3 | 2.53, 3H, s | 21.8 | C-5, C-6, C-7 | 2.56, 3H, s | 22.0 | C-5, C-6, C-7 |