Table 33.

Humulane Sesquiterpenoids (1,1,4,8-Tetramethylcycloundecane, 9CI) and Caryophyllane Sesquiterpenoids (2,6,10,10-Tetramethylbicyclo[7.2.0]undecane, 9CI).

Name	Alternative Name(s)	CAS Number	References
Humulanes
α-Humulene (401)	2,6,9-Humulatriene	[6753-98-6]	[19, 27, 28, 32, 40, 43, 66]
14-Hydroxy-α-humulene (402)		[108043-85-2]	[27]
Humulene epoxide I (403)	2,3-Epoxy-6,9-humuladiene	[19888-33-6]	[45]
Humulene epoxide II (404)	6,7-Epoxy-2,9-humuladiene	[19888-34-7]	[27, 45]
Caryophyllanes
β-Caryophyllene (405)	(E)-3(15),6-Caryophylladiene	[87-44-5]	[19, 22, 23, 24, 26, 27, 29, 32, 36, 37, 40, 41, 42, 43, 45, 48, 49, 51, 66, 72, 73, 74, 112, 140]
γ-Caryophyllene (406)	Isocaryophyllene (Z)-3(15),6-Caryophylladiene	[118-65-0]	[31]
(1R,3Z,9S)-Bicyclo[7.2.0]undec-3-ene, 4,11,11-trimethyl-8-methylene- (407)		[136296-35-0]	[50]
Caryophylladienol I (408)	Caryophyllenol Bicyclo[7.2.0]undecan-5-ol, 10,10-dimethyl-2,6-bis(methylene)-, (1S,5S,9R)-Caryophylla-4(12),8(13)-dien-5β-ol	[19431-80-2] [38284-26-3]	[28, 32, 43]
Caryophylladienol II (409)	Caryophyllenol Bicyclo[7.2.0]undecan-5-ol, 10,10-dimethyl-2,6-bis(methylene)-, (1S,5R,9R)-Caryophylla-4(12),8(13)-dien-5α-ol	[19431-79-9] [38284-26-3]	[28, 32, 43]
Caryophyllene oxide (410)	Isocaryophyllene oxide 6,7-Epoxy-3(15)-caryophyllene	[1139-30-6] [113877-94-6] [17627-43-9]	[9, 19, 23, 25, 27, 30, 32, 34, 43, 45, 48, 49, 50, 66]
cis-Caryophyllene oxide (411)	5-Oxatricyclo[8.2.0.04,6]dodecane, 4,12,12-trimethyl-9-methylene-, (1R,4S,6R,10S)-	[60594-23-2]	[32]