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. Author manuscript; available in PMC: 2019 Oct 30.
Published in final edited form as: Chem Commun (Camb). 2018 Oct 30;54(87):12286–12301. doi: 10.1039/c8cc07093h

Scheme 6.

Scheme 6

Our stereospecific, nickel-catalyzed arylation of benzylic ammonium triflates with boronic acids to form enantioenriched diarylethanes. *tBu-XantPhos used as ligand in place of P(oTol)3.