Table 2.
Summary of the textural characteristics of a permanent porous glass derived from ZIF-76-mbIm
ZIF-76-mbIm | agZIF-76-mbIm | |
---|---|---|
Uptake of CO2 (1 bar, 273 K) | 10.0 wt% | 7.0 wt% |
Surface area from N2 / 77 K dataa | 1173 | d |
Surface area from CO2/273 K dataa | 643 | 375 |
Pore volume from N2/77 K datab | 0.50 | d |
Pore volume from CO2/273 K datab | 0.17 | 0.12 |
Isosteric heat of adsorption, Qst (CO2)c | −26.3 | −29.3 |
aIn cm2 g–1 using the BET model (N2) or NLDFT fitting (CO2)
bVolume accessible to adsorbate in cm3 g–1 at 1 bar using the density of liquid adsorbate (N2) or NLDFT fitting
cIn kJ mol–1 at zero loading
dNot measurable due to diffusion limitations