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. 2018 Nov 22;6:563. doi: 10.3389/fchem.2018.00563

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Copyright © 2018 Vasdev, Gaudin, Preston, Jogy, Giles and Crowley.

This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

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Molecular structures of C_q and C_iq. X-ray structure of C_q: (A) ellipsoid side view, (B) tube side view, and (C) tube top view showing paddle-like array of quinoline panels over palladium(II) center. Solvent molecules and counterions have been omitted for clarity. Ellipsoids are shown at 50% probability. DFT optimized (BP86 def2-SVP) model of C_iq; (D) side view and (E) top view showing lantern-shaped structure. Colors: carbon gray, nitrogen blue, palladium magenta, hydrogen white.