Skip to main content
. Author manuscript; available in PMC: 2019 Jan 31.
Published in final edited form as: J Am Chem Soc. 2018 Jan 19;140(4):1275–1279. doi: 10.1021/jacs.7b13482

Table 1.

Influence of base in the amination of α-methyl allyl acetate 1a to form allylic amine 3a.a

graphic file with name nihms-993301-t0008.jpg
a

All reactions were performed on a 0.44 mmol scale. Enantioselectivities were determined by chiral stationary phase HPLC analysis. See Supporting Information for further experimental details.

b

Conversion was determined by 1H NMR.

c

Cs2CO3 (200 mol%).

d

Yield of material isolated by silica gel chromatography.