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IR spectral assignment of L and its metal complexes.
| Ligand/complexes | υ(NH2) | υ(C–S) cm−1 | Δ(NH2) cm−1 |
|---|---|---|---|
| L | 3195.31,b | 1430, str. | 1536.55,str. |
| Co(L)2Cl2 | 3414.06,b | 1429.98,s | 1536.92,s |
| Ni(L)2Cl2 | 3414.48,b | 1429.82,s | 1537.62,s |
| Cu(DT)2Cl2 | 3424.82, b | 1407.37,s |
