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. 2011 Jul 4;16(7):5674–5681. doi: 10.3390/molecules16075674

Table 2.

1H- and 13C-NMR data of 1 and 2 in CD3OD at 400 MHz and 100 MHz, J in Hz.

No. 1 2
δH δC δH δC
1 129.8 131.4
2 6.78 (1H, d, J = 1.2 Hz) 115.1 6.59 (1H, d, J = 1.6 Hz) 117.0
3 146.3 146.0
4 146.6 144.6
5 6.69 (1H, d, J = 8.2 Hz) 116.4 6.57 (1H, d, J = 8.0 Hz) 116.3
6 6.66 (1H, dd, J = 8.2, 1.2 Hz) 119.5 6.48 (1H, dd, J = 8.0, 1.6 Hz) 121.4
7 4.50 (1H, dd, J = 10.2, 2.8 Hz) 78.7 2.67 (2H, t, J = 7.2 Hz) 36.7
8 3.90 (1H, dd, J = 12.0, 2.8 Hz) 72.6 3.94 (1H, m) 72.0
3.61 (1H, dd, J = 12.0, 10.2 Hz) 3.63 (1H, m)
1′ 127.8 127.8
2′ 7.01 (1H, d, J = 2.0 Hz) 115.5 7.06 (1H, d, J = 1.2 Hz) 115.2
3′ 146.9 146.8
4′ 149.8 149.6
5′ 6.73 (1H, d, J = 8.2 Hz) 116.5 6.77 (1H, d, J = 8.4 Hz) 116.5
6′ 6.91 (1H, dd, J = 8.2, 2.0 Hz) 123.1 6.91 (1H, dd, J = 8.4, 1.2 Hz) 123.0
7′ 6.25 (1H, d, J = 16.0 Hz) 147.8 6.27 (1H, d, J = 16.0 Hz) 147.1
8′ 7.55 (1H, d, J = 16.0 Hz) 114.6 7.56 (1H, d, J = 16.0 Hz) 115.2
9′ 168.2 168.4
1′′ 4.51 (1H, d, J = 7.6 Hz) 99.9 4.49 (1H, d, J = 8.0 Hz) 102.4
2′′ 3.40 (1H, m) 74.3 4.80 (1H, t, J = 8.0 Hz) 75.1
3′′ 5.25 (1H, t, J = 8.8 Hz) 76.0 3.56 (1H, t, J = 8.8 Hz) 76.2
4′′ 3.62 (1H, m) 70.2 3.38 (1H, m) 71.7
5′′ 3.67 (1H, m) 78.5 3.44 (1H, m) 76.9
6′′ 3.45 (1H, dd, J = 11.2, 5.2 Hz) 67.8 3.65 (1H, dd, J = 10.8, 5.0 Hz) 67.9
3.72 (1H, dd, J = 11.2, 1.7 Hz) 4.00 (1H, dd, J = 10.8, 1.2 Hz)
1′′′ 4.73 (1H, d, J = 0.8 Hz) 102.3 4.74 (1H, d, J = 1.6 Hz) 102.2
2′′′ 3.85 (1H, m) 72.0 3.84 (1H, m) 72.3
3′′′ 3.70 (1H, m) 72.4 3.70 (1H, m) 72.2
4′′′ 3.37 (1H, m) 74.0 3.37 (1H, m) 74.0
5′′′ 3.71 (1H, m) 69.9 3.70 (1H, m) 69.8
6′′′ 1.26 (1H, d, J = 6.5 Hz) 18.0 1.26 (1H, d, J = 6.0 Hz) 18.1