Table 2.
1H- and 13C-NMR data of 1 and 2 in CD3OD at 400 MHz and 100 MHz, J in Hz.
No. | 1 | 2 | |||
---|---|---|---|---|---|
δH | δC | δH | δC | ||
1 | 129.8 | 131.4 | |||
2 | 6.78 (1H, d, J = 1.2 Hz) | 115.1 | 6.59 (1H, d, J = 1.6 Hz) | 117.0 | |
3 | 146.3 | 146.0 | |||
4 | 146.6 | 144.6 | |||
5 | 6.69 (1H, d, J = 8.2 Hz) | 116.4 | 6.57 (1H, d, J = 8.0 Hz) | 116.3 | |
6 | 6.66 (1H, dd, J = 8.2, 1.2 Hz) | 119.5 | 6.48 (1H, dd, J = 8.0, 1.6 Hz) | 121.4 | |
7 | 4.50 (1H, dd, J = 10.2, 2.8 Hz) | 78.7 | 2.67 (2H, t, J = 7.2 Hz) | 36.7 | |
8 | 3.90 (1H, dd, J = 12.0, 2.8 Hz) | 72.6 | 3.94 (1H, m) | 72.0 | |
3.61 (1H, dd, J = 12.0, 10.2 Hz) | 3.63 (1H, m) | ||||
1′ | 127.8 | 127.8 | |||
2′ | 7.01 (1H, d, J = 2.0 Hz) | 115.5 | 7.06 (1H, d, J = 1.2 Hz) | 115.2 | |
3′ | 146.9 | 146.8 | |||
4′ | 149.8 | 149.6 | |||
5′ | 6.73 (1H, d, J = 8.2 Hz) | 116.5 | 6.77 (1H, d, J = 8.4 Hz) | 116.5 | |
6′ | 6.91 (1H, dd, J = 8.2, 2.0 Hz) | 123.1 | 6.91 (1H, dd, J = 8.4, 1.2 Hz) | 123.0 | |
7′ | 6.25 (1H, d, J = 16.0 Hz) | 147.8 | 6.27 (1H, d, J = 16.0 Hz) | 147.1 | |
8′ | 7.55 (1H, d, J = 16.0 Hz) | 114.6 | 7.56 (1H, d, J = 16.0 Hz) | 115.2 | |
9′ | 168.2 | 168.4 | |||
1′′ | 4.51 (1H, d, J = 7.6 Hz) | 99.9 | 4.49 (1H, d, J = 8.0 Hz) | 102.4 | |
2′′ | 3.40 (1H, m) | 74.3 | 4.80 (1H, t, J = 8.0 Hz) | 75.1 | |
3′′ | 5.25 (1H, t, J = 8.8 Hz) | 76.0 | 3.56 (1H, t, J = 8.8 Hz) | 76.2 | |
4′′ | 3.62 (1H, m) | 70.2 | 3.38 (1H, m) | 71.7 | |
5′′ | 3.67 (1H, m) | 78.5 | 3.44 (1H, m) | 76.9 | |
6′′ | 3.45 (1H, dd, J = 11.2, 5.2 Hz) | 67.8 | 3.65 (1H, dd, J = 10.8, 5.0 Hz) | 67.9 | |
3.72 (1H, dd, J = 11.2, 1.7 Hz) | 4.00 (1H, dd, J = 10.8, 1.2 Hz) | ||||
1′′′ | 4.73 (1H, d, J = 0.8 Hz) | 102.3 | 4.74 (1H, d, J = 1.6 Hz) | 102.2 | |
2′′′ | 3.85 (1H, m) | 72.0 | 3.84 (1H, m) | 72.3 | |
3′′′ | 3.70 (1H, m) | 72.4 | 3.70 (1H, m) | 72.2 | |
4′′′ | 3.37 (1H, m) | 74.0 | 3.37 (1H, m) | 74.0 | |
5′′′ | 3.71 (1H, m) | 69.9 | 3.70 (1H, m) | 69.8 | |
6′′′ | 1.26 (1H, d, J = 6.5 Hz) | 18.0 | 1.26 (1H, d, J = 6.0 Hz) | 18.1 |