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. 2011 Jun 28;16(7):5460–5495. doi: 10.3390/molecules16075460

Table 3.

ATH of acetophenone catalyzed by immobilized 1b.

Entry Catalyst config. Substrate Solution S/C [a]; Time; Temp.;
Conversion (%)		 % ee
(config) [b] 		Ref. [c]
1 (S,S) [d] DHIQ [e] HCOOH/Et3N; acetonitrile 200; 7 h; r.t.; 99 89% (R) [67]
2 (S,S) [f] acetophenone H2O/HCOONa; Et4N+Br 100; 5 h; 30 °C; >99 93% (S) [68]

[a] Molar ratio substrate/catalyst; [b] See corresponding references for details on determination of ee and product configuration; [c] Reference containing data for a given entry; [d] 1b was immobilized in functionalized MCM-41; [e] DHIQ = 1-methyl-3,4-dihydroisoquinoline; [f] 1b was immobilized in a nanocage of SBA-16.