Table 2.
Comp. | Solvent | δNH | δHB | 1J(C,HB) | δHA | 1J(C,HA) | 2J(H,H) |
---|---|---|---|---|---|---|---|
1a | CDCl3 | 6.35 | 4.89 | 159 | 4.51 | 157 | 11.5 |
DMSO | 9.44 | 4.69 | 4.40 | 9.6 | |||
1b | CDCl3 | 4.96 | 4.82 | 11.0 | |||
DMSO | 5.17 | 4.87 | 11.3 | ||||
1c | CDCl3 | 6.49 | 4.81 | 159 | 4.66 | 157 | 11.6 |
DMSO | 9.67 | 4.61 | 158 | 4.56 | 157 | 9.9 | |
1d | CDCl3 | 6.55 | 4.86 | 4.57 | 11.8 | ||
DMSO | 9.62 | 4.67 | 4.53 | 9.7 | |||
1e | CDCl3 | 7.37 | 5.19 | 160 | 4.74 | 158 | 14.6 |
DMSO | 9.78 | 4.93 | 158 | 4.48 | 156 | 11.1 | |
1f | CDCl3 | 6.45 | 4.91 | 159 | 4.63 | 156.4 | 11.8 |
DMSO | 9.58 | 4.67 | 160 | 4.57 | 158.7 | 9.6 | |
1g | CDCl3 | 6.56 | 4.86 | 4.62 | 11.3 | ||
DMSO | 9.65 | 4.62 | 4.59 | 9.7 | |||
1h | CDCl3 | 6.45 | 4.92 | 158 | 4.63 | 156 | 11.5 |
DMSO | 9.62 | 4.68 | 159 | 4.59 | 157 | 9.7 | |
1i | CDCl3 | 4.91 | 4.84 | 11.0 | |||
DMSO | 5.18 | 4.85 | 11.4 | ||||
2a | CDCl3 | 10.88 | 6.28 | 5.76 | 14.1 | ||
DMSO | 10.10 | 5.99 | 5.49 | 15.0 | |||
2b | CDCl3 | 6.82 | 152.1 | 6.59 | 146.3 | 15.6 | |
DMSO | 6.45 | 152.2 | 5.77 | 146.2 | 16.0 | ||
2c | CDCl3 | 10.98 | 6.35 | 153.1 | 5.97 | 147.1 | 13.6 |
DMSO | 10.48 | 5.97 | 151.1 | 5.66 | 149.1 | 15.1 | |
2d | CDCl3 | 10.80 | 6.16 | 6.11 | 14.1 | ||
DMSO | 10.15 | 5.90 | 150.1 | 5.62 | 149.2 | 14.9 | |
2e | CDCl3 | 10.31 | 6.30 | 6.06 | 14.1 | ||
DMSO | 10.20 | 5.97 | 5.64 | 15.6 | |||
2f | CDCl3 | 10.92 | 6.38 | 150.6 | 5.92 | 146.5 | 13.6 |
DMSO | 10.34 | 6.08 | 151.9 | 5.63 | 146.4 | 15.3 | |
2g | CDCl3 | 10.88 | 6.24 | 6.10 | 13.7 | ||
DMSO | 10.31 | 5.94 | 5.46 | 14.9 | |||
2h | CDCl3 | 6.84 | 6.62 | 15.8 | |||
DMSO | 6.39 | 5.77 | 16.2 | ||||
3a | CDCl3 | 10.96 | 6.40 | 150.7 | 5.89 | 146.5 | 13.9 |
DMSO | 10.21 | 6.08 | 151.1 | 5.56 | 145.4 | 15.1 | |
3b | CDCl3 | 10.95 | 6.40 | 151.4 | 5.89 | 146.3 | 13.9 |
DMSO | 10.12 | 6.07 | 152.4 | 5.53 | 146.3 | 15.0 | |
3c | CDCl3 | 10.92 | 6.32 | 150.1 | 5.86 | 146.2 | 13.8 |
DMSO | 10.28 | 6.08 | 152.1 | 5.56 | 146.4 | 15.1 | |
3d | CDCl3 | 10.96 | 6.40 | 148.3 | 5.89 | 146.2 | 13.9 |
DMSO | 10.12 | 6.07 | 5.53 | 15.2 | |||
3e | CDCl3 | 6.73 | 152.5 | 6.56 | 150.2 | 16.1 | |
DMSO | 6.48 | 152.5 | 5.78 | 147.5 | 16.5 | ||
4a | CDCl3 | 8.30 | 4.52 | and | 4.47 | 16.7 | |
DMSO | 9.74 | 4.84 | and | 4.74 | 16.5 | ||
4f | CDCl3 | 6.42 | 4.69 | and | 4.65 | 16.4 | |
5a | DMSO | 9.91 | 4.72 | and | 4.65 | 16.0 | |
5f | DMSO | 9.97 | 4.64 | and | 4.60 | 16.2 |