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(i) Chemical structure of part of the crystallographically determined complex 42, with a 2.323(2) Å Pd–P distance (from the crystal structure) used in the calculation of buried volume, 36.2%Vbur. (ii) Chemical structure of the bond-length-modified, crystal-structure-informed palladium complex of ligand 29e in complex 42 (2.280 Å Pd–P distance was used in the buried volume calculation), 36.9%Vbur.
