Optical rotation |
α |
The rotation of linearly polarized light as it travels through certain non-racemic materials. |
Optical rotatory dispersion |
ORD |
The variation in the specific rotation of a substance with a change in the wavelength of light. May be used to determine the absolute configuration of metal complexes, for example. |
Circular dichroism |
CD |
A form of spectroscopy based on the differential absorption (Δε) of left- and right-handed circularly polarized light (LCP and RCP) in non-racemic molecules. |
Exction-coupled circular dichroism(Exciton Chirality) |
ECCD |
Circular dichroism coming from an exciton couplet: Two chromophores presenting in a molecule in close proximity to one another, who interact and give rise to differentiation of the energies of the transitions. |
Fluorescence-detected CD |
FDCD |
Circular dichroism derived from the differential emission of light from a sample excited with LCP and RCP radiation when the analyte is chiral, fluorescent, and the quantum yield is the same for both circularly polarized components. |
Diffrentialcircularly polarized fluorescence excitation |
CPE(ΔF) |
The differential emission of light from a sample excited with LCP and RCP radiation. The quantum yield does not have to be the same for both circularly polarized components |
Circularly polarized luminescence |
CPL |
The anisotropic emission of circularly polarized light originated from non-polarized excitation. |