Table 6.
Entry | Aromatic Amine | 5- | N- | Yield / % a |
---|---|---|---|---|
8a | 4-Dodecylaniline | n-C12H25 | H | 77.7 |
8b | 4- n-Butylaniline | n-C4H9 | H | 64.1 |
8c | p-Toluidine | Me | H | 84.0 |
8d | 4-Fluoroaniline | F | H | 75.7 |
8e | Aniline | H | H | 78.9 |
8f | N-Me-p-toluidine | Me | Me | 29.3 |
a Isolated yield, estimated from HPLC areas. Reaction conditions: C60O 100 mg, 0.136 mmol; aromatic amines 1.357 mmol; Sepiolite 2.0 g; chlorobenzene 100 mL, 100 °C.