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. 2012 Mar 9;17(3):3025–3043. doi: 10.3390/molecules17033025
Hydrogens Compound/ δH (ppm), JH (Hz)
8 9 11 12 14 16 18
2 4,5 (1H, m) 4.70 (1H, q) 3.48 ( q, 6; 10) 4.07 ( q, 6; 10) 4.08 (1H, q, 6, 10) 3.6 ( dd, 6.2, 11) 4.5 ( m)
3 3.0 ( brd, 10.7) 1.9 (m) 3.28 (1H, m) 2.22 (1H) 3.0 ( dt, 13.1, 4.1) 1.95 (dd, 2.9, 10.7) 3.0 ( brd, 10.7) 2.05–1.9 (m)
5 3.11 ( td, 9, 3.2) 2.25 (m) 3.48 (1H, m) 2.40 (m, 13.8) 3.1 ( td, 7.6, 2.8) 2.3 (m) 3.1 ( td, 9, 3.2) 2.25 (m)
6 2.05 ( m) 1.55 (m) 2.20 (1H, m) 1.80 (1H, m) 2.4 ( m) 1.5 (m) 2.05–1.9 ( m) 1.6–1.35 (m)
9 6.83 ( d, 8.7) 6.82 (2H, 8.0) 6.56 (3H, m) 6.9 (3H, m) 7.17 (3H, m) 6.75 ( d, 1.7) 6.83 ( d, 8.7)
10 7.07 ( t, 8.7) 7.08 (1H, d, 8.0) 6.56 (3H, m) 6.9 (3H, m) 7.17 (3H, m) 7.07 ( t, 8.7)
11 6.8 ( d, 8.7) 6.82 (2H, 8.0) 6.56 (3H, m) 6.9 (3H, m) 7.17 (3H, m) 6.6 ( dd, 1.7, 7) 6.8 ( d, 8.7)
12 8.13 (1H, ) 6.7 ( d, 7)
14 1.73 ( qt, 13.4) 1.5 (brd, 13) 2.0 (1H) 1.60 (1H, m) 1.8 ( qt, 13.1, 4.0) 1.5 (m) 1.7 ( qt, 13, 4) 1.6–1.35 (m)
15 1.6 ( m) 1.05 (m) 3.22 ( m, 14.5, 7.0) 1.6 ( m) 1.2 (dd, 4.5, 13.4) 1.6–1.35 ( m) 1.3–1.05 (m)
16 1.95 ( m) 1.35 (m) 1.30 (1H, m) 2.04 (1H, m) 1.6 ( m) 1.4 (dt, 14.0, 3.4) 2.05–1.9 ( m) 1.6–1.35 (m)
17 2.0 ( m) 1.1 (m) 1.10 (1H, dq, 14.7) 2.18 (1H, m) 2.0 ( dd, 2.6, 12.3) 1.1 (dt, 12.6, 2.5) 2.05–1.9 ( m) 1.3–1.05 (m)
18 0.6 ( t, 7.1) 0.63 (3H, t, 6.9) 0.6 (3H, t, 6) 0.72 (3H, t) 0.73 (3H, t) 0.7 ( t, 7.3) 0.6 ( t, 7)
19 1.2 ( dq, 14, 7.1) 0.8 (dq, 14, 7.1) 0.75 (1H, q, 6.9) 1.22 (1H, m) 1.5 ( m) 0.9 (dq, 14.3, 7.3) 1.3–1.05 ( m) 0.8 (dq, 14, 7)
21 2.23 (1H, s) 2.20 (1H, s) 2.16 (1H, s) 2.28 (1H, s) 2.2 (1H, s) 2.2 ( s)
10-OCH3 3.8 (3H, s)
12-OCH3 3.87 (3H, s) 3.90 (3H, s) 3.78 (3H, s) 3.87 ( s)
15-OCH3 3.33 (3H, s)
COCH3 2.2 (3H, s) 2.22 (3H, s) - 2.32 (3H, s) 2.27 (3H, s)
COCH2CH3 2.6 ( dq, 13, 6.5) 2.4 (m)
COCH2CH3 1.3 ( t, 6.5)
OH 10.83 ( s)
NH 3.35 (1H, s)