Table 2.

Allyl-amine 8–12 yields obtained under solvent free conditions and with the reflux method.

Allyl amine	X	MP (°C)	Reflux procedure Yield (%) 8–10 h	Solvent free conditions Yield (%) 30 min
14	H	Oil a	60	96
15	4-CH3	Oil b	45	99
16	4-OCH3	67 c	55	99
17	4-Cl	83 c	72	98
18	4-Br	86–87 c	75	98
19	4-F	60 c	70	99

^a Lit. [20]; ^b lit. [21]; ^c lit. [22].