Table 3.

The mass spectral data of some major products from aldehyde-mediated condensation reactions of anthocyanins and/or flavan-3-ols [63,64,66,128].

Compounds	Molecular ion M+ (m/z)	Fragment ion M+ (m/z)
Petunidin-glucoside-8-ethyl-(epi)catechin	795	633,505,481,435,328
Malvidin-glucoside-8-ethyl-gallocatechin	825
Malvidin-glucoside-8-ethyl-(epi)catechin	809	657,517,357,341,331
Malvidin-acetylglucoside-8-ethyl-(epi)catechin	851
Malvidin-coumaroylglucoside-8-ethyl-(epi)catechin	955	803,665,647,357,341
Peonidin-glucoside-8-ethyl-(epi)catechin	779
Peonidin-coumaroylglucoside-8-ethyl-(epi)catechin	925	635,617,327
Malvidin-glucoside-4-methyl-(epi)catechin	795	505
Malvidin-glucoside-4-2methylpropyl-(epi)catechin	837	547
Malvidin-glucoside-4-3methylbutyl-(epi)catechin	851	561
Malvidin-glucoside-4-2methylbutyl-(epi)catechin	851	561
Malvidin-glucoside-4-benzyl-(epi)catechin	871	581
Malvidin-glucoside-4-propyl-(epi)catechin	823	533
Malvidin-glucoside-4-ethyl-PC dimer	1097	519
Malvidin-glucoside-4-3methylbutyl-PC dimer	1139
Malvidin-glucoside-4-benzyl-PC dimer	1159	707
Malvidin-glucoside-4-propyl-PC dimer	1111	959
Malvidin-glucoside-4-ethyl-epicatechin-3-O-gallate	961	799,519
Malvidin-glucoside-4-ethyl-B2-3'-O-gallate	1249
Malvidin-glucoside-4-3methylbutyl-epicatechin-3-O-gallate	1003
Malvidin-glucoside-4-3methylbutyl-B2-3'-O-gallate	1291
Malvidin-glucoside-4-benzyl-epicatechin-3-O-gallate	1023	719
Malvidin-glucoside-4-benzyl-PB2-3'-O-gallate	1311	419,581
Malvidin-glucoside-4-propyl-epicatechin-3-O-gallate	975	813,671
Malvidin-glucoside-4-propyl-PB2-3'-O-gallate	1263	821
Malvidin-glucoside-4-methyl-epicatechin-3-O-gallate	947	785,343
Malvidin-glucoside-4-methyl-PB2-3'-O-gallate	1235	1073,793
Malvidin-glucoside-4-isobutyl-epicatechin-3-O-gallate	989	385
Malvidin-glucoside-4-isobutyl-PB2-3'-O-gallate	1277	835