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. 2018 Nov 30;8:17483. doi: 10.1038/s41598-018-35933-z

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© The Author(s) 2018

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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The polycondensation approach and its comparison with monodisperse oligomers. (a) Schematic representation of the polycondensation approach with starting unit (phenylacetylene), monomer 13 and chain stopper 1. (b) SEC traces of a step-growth approach with monofunctional monomers (brown) in comparison to the monodisperse protected oligomers - monomer 2 (black), dimer 4 (red), trimer 6 (blue), tetramer 8 (pink) and pentamer 10 (green) and the building block 1 (grey). The trimer 4 is most abundant in the mixture. (c) Absorption (dotted) and photoluminescence (dotted) spectra of the polycondensation approach (brown), in comparison to the oligomers.