Table 3.
Alcohol | Products | High resolution | Elemental composition | Yield% a | ||
---|---|---|---|---|---|---|
MW | IR | |||||
4c n = 1 | 258.1385 b/258.1409 c (−8.9) d | C20H18 | 60 | 58 | ||
4d n = 2 | 348.1884 b/348.1878 c (1.6) d | C27H24 | 40 | 22 | ||
4e n = 3 | 438.2355 b/438.2348 c (1.8) d | C34H30 | 0 | 20 | ||
5c n = 1 | 300.1885 b/300.1878 c (1.8) d | C23H24 | 55 | 0 | ||
5d n = 2 | 404.2498 b/404.2504 c (1.8) d | C31H32 | 28 | 0 | ||
5e n = 3 | 508.3136 b/508.3130 c (1.6) d | C39H40 | 12 | 0 | ||
5f n = 4 | 612.3762 b/612.3756 c (1.6) d | C47H48 | 5 | 0 | ||
5g n = 0 | 226.1346 b/226.1358 (−5.4) d | C16H18O | 0 | 65 | ||
5h n = 1 | 330.1990 b/330.1984 c (1.9) d | C24H26O | 0 | 25 | ||
5i n = 2 | 434.2614 b/434.2610 c (1.8) d | C32H34O | 0 | 10 | ||
6c n = 1 | 348.1755 b/348.1757 c (3.8) d | C23H24O3 | 35 | 8 | ||
6d n = 2 | 468.2345 b/468.2343 c (4.6) d | C31H32O4 | 65 | 92 |
a Convertion and composition of reaction mixture was determinate by GC-EIMS and HRMS; b Observed m/z; c Estimated m/z; d Error (ppm).