Table 3.
Compound | ν(O-H) | ν(C=O) | ν(C=C) | ν(C-O) + δ(OH) | ν(C-O-C) | γw(H2O) |
---|---|---|---|---|---|---|
HL | 3,200–2,600 b, m | 1,654 s; 1,615 s |
1,587 s | 1,357 m; 1,298 s |
1,255 s | - |
[Mg(L)2(H2O)2]·H2O (1) |
3,600–2,600 b, m | 1,634 s | 1,583 s | 1,361 m; 1,297 w |
1,251 s | 422 w |
[Zn(L)2(H2O)2]·0.5H2O (2) |
3,600–2,600 b, m | 1,632 s | 1,580 s | 1,355 m; 1,297 w |
1,250 s | 546 w |
b: broad; m: medium; s: strong; w: weak.