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. 2013 Jul 1;18(7):7631–7645. doi: 10.3390/molecules18077631

Table 8.

Thermal degradation data (in synthetic air) for the complexes.

Complex Step Thermal effect Temperature range/°C Δmexp/% Δmcalc/% Chemical process
[Mg(L)2(H2O)2]·H2O
(1)
1. Endothermic 52–90 3.0 3.3 H2O loss
2. Endothermic 120–160 3.1 3.3 H2O loss
3. Endothermic 170–206 3.2 3.3 H2O loss
4. Exothermic 408–900 56.3 Partial oxidative degradation of organic part
Residue (MgO + organic residue) 34.4
[Zn(L)2(H2O)2]·0.5H2O
(2)
1. Endothermic 54–75 1.7 1.6 0.5 H2O loss
2. Endothermic 85–128 6.1 6.2 2H2O loss
3. Exothermic 300–750 78.5 78.3 Oxidative degradation of organic part
Residue (ZnO) 13.7 13.9