Table 8.
Complex | Step | Thermal effect | Temperature range/°C | Δmexp/% | Δmcalc/% | Chemical process |
---|---|---|---|---|---|---|
[Mg(L)2(H2O)2]·H2O
(1) |
1. | Endothermic | 52–90 | 3.0 | 3.3 | H2O loss |
2. | Endothermic | 120–160 | 3.1 | 3.3 | H2O loss | |
3. | Endothermic | 170–206 | 3.2 | 3.3 | H2O loss | |
4. | Exothermic | 408–900 | 56.3 | Partial oxidative degradation of organic part | ||
Residue (MgO + organic residue) | 34.4 | |||||
[Zn(L)2(H2O)2]·0.5H2O
(2) |
1. | Endothermic | 54–75 | 1.7 | 1.6 | 0.5 H2O loss |
2. | Endothermic | 85–128 | 6.1 | 6.2 | 2H2O loss | |
3. | Exothermic | 300–750 | 78.5 | 78.3 | Oxidative degradation of organic part | |
Residue (ZnO) | 13.7 | 13.9 |