Table 2.
Dehalogenation of haloaromatics compounds using indium metal in IL a.
| Entry | Substrate | Product | Yield b (%) | Recovery b (%) | |
|---|---|---|---|---|---|
| 1 |
|
3 |
|
20 | 80 |
| 2 |
|
4 |
|
>99 | - |
| 3 |
|
3 |
|
80 | 20 |
| 4 |
|
5 |
|
76 | 24 |
| 5 |
|
6 |
|
10 | 90 |
| 6 |
|
7 |
|
>99 | - |
| 7 |
|
8 |
|
>99 | - |
| 8 |
|
9 |
|
>99 | - |
| 9 |
|
10 |
|
11 | 89 |
| 10 c |
|
11 |
|
>99 | - |
| 11 c |
|
12 |
|
>99 | - |
| 12 |
|
13 |
|
>99 | - |
a In (1 equiv.), in IL (2 equiv.), 95 °C, 14 h; b Values of substrate and product were determined by GC-MS; c Reaction time: 5 h.