Table 4.
1H- and 13C-NMR data for compound 3 in C5D5N (500 MHz for 1H and 125 MHz for 13C).
| No. | δC | δH (J in Hz) | No. | δC | δH (J in Hz) |
|---|---|---|---|---|---|
| 1 | 39.5 | 1.02 (m), 1.74 (m) | 23 | 23.2 | 2.22 (m), 2.50 (m) |
| 2 | 28.0 | 1.85 (m), 1.93 (m) | 24 | 125.9 | 5.28 (t, 7.0) |
| 3 | 78.7 | 3.50 (dd, 5.0, 11.5) | 25 | 131.1 | — |
| 4 | 40.4 | — | 26 | 25.8 | 1.62 (s) |
| 5 | 61.4 | 1.41 (d, 10.5) | 27 | 17.8 | 1.63 (s) |
| 6 | 80.2 | 4.42 (ddd, 3.0, 10.5, 10.5) | 28 | 31.8 | 2.08 (s) |
| 7 | 45.2 | 1.94 (m), 2.50 (m) | 29 | 16.4 | 1.61 (s) |
| 8 | 41.1 | — | 30 | 17.2 | 0.81 (s) |
| 9 | 50.0 | 1.51 (m) | 1' | 106.0 | 5.02 (d, 8.0) |
| 10 | 39.7 | — | 2' | 75.5 | 4.09 (dd, 8.0, 8.0) |
| 11 | 31.0 | 1.51 (m), 2.05 (m) | 3' | 79.7 | 4.25 (m) |
| 12 | 70.1 | 4.11 (m) | 4' | 71.9 | 4.21 (dd, 8.0, 9.0) |
| 13 | 49.2 | 1.98 (dd, 10.5, 10.5) | 5' | 78.2 | 3.95 (m) |
| 14 | 51.3 | — | 6' | 63.1 | 4.37 (dd, 5.0, 12.0) |
| 15 | 30.6 | 1.06 (m), 1.65 (m) | 4.52 (dd, 1.5, 12.0) | ||
| 16 | 26.6 | 1.30 (m), 1.75 (m) | 1'' | 98.7 | 4.96 (d, 8.0) |
| 17 | 51.5 | 2.48 (m) | 2'' | 72.6 | 4.38 (dd, 8.0, 8.5) |
| 18 | 17.60 | 1.17 (s) | 3'' | 75.3 | 4.15 (dd, 3.0, 8.5) |
| 19 | 17.55 | 1.03 (s) | 4'' | 69.6 | 4.27 (m) |
| 20 | 83.0 | — | 5'' | 66.9 | 3.75 (dd, 3.0, 11.0) |
| 21 | 22.2 | 1.56 (s)
3.63 (1H, m, overlapped) |
4.26 (m) | ||
| 22 | 36.1 | 1.79 (m), 2.38 (m) |