Table 8.
1H- and 13C-NMR data for compound 7 in C5D5N (500 MHz for 1H and 125 MHz for 13C).
| No. | δC | δH (J in Hz) | No. | δC | δH (J in Hz) |
|---|---|---|---|---|---|
| 1 | 39.2 | 0.88 (m), 1.51 (m) | 23 | 27.8 | 1.74 (m), 2.81 (m) |
| 2 | 28.0 | 1.84 (m) | 24 | 124.8 | 5.41 (t, 7.0) |
| 3 | 78.6 | 3.52 (dd, 5.0, 11.0) | 25 | 130.4 | — |
| 4 | 40.4 | — | 26 | 25.9 | 1.71 (s) |
| 5 | 61.5 | 1.37 (d, 10.5) | 27 | 17.9 | 1.62 (s) |
| 6 | 80.0 | 4.38 (m) | 28 | 31.8 | 2.06 (s) |
| 7 | 45.1 | 1.88 (m), 2.47 (m) | 29 | 16.3 | 1.59 (s) |
| 8 | 41.2 | — | 30 | 16.9 | 0.73 (s) |
| 9 | 50.4 | 1.43 (m) | 1' | 105.9 | 5.01 (d, 7.5) |
| 10 | 39.8 | — | 2' | 75.5 | 4.09 (dd, 7.5, 8.0) |
| 11 | 28.1 | 1.22 (m), 2.15 (m) | 3' | 79.7 | 4.24 (dd, 8.0, 9.0) |
| 12 | 77.1 | 4.12 (m) | 4' | 72.5 | 4.11 (dd, 8.0, 9.0) |
| 13 | 48.9 | 1.98 (dd, 10.5, 10.5) | 5' | 77.9 | 3.98 (m) |
| 14 | 51.1 | — | 6' | 63.1 | 4.37 (dd, 5.0, 12.0) |
| 15 | 32.7 | 1.10 (m), 1.66 (m) | 4.51 (dd, 2.0, 12.0) | ||
| 16 | 29.4 | 1.44 (m), 1.78 (m) | 1'' | 101.2 | 4.98 (d, 7.5) |
| 17 | 49.6 | 2.77 (m) | 2'' | 75.3 | 3.90 (dd, 7.5, 8.0) |
| 18 | 17.2 | 1.09 (s) | 3'' | 78.6 | 4.27 (dd, 8.0, 9.0) |
| 19 | 17.7 | 0.91 (s) | 4'' | 71.8 | 4.22 (dd, 9.0, 9.0) |
| 20 | 138.4 | — | 5'' | 78.2 | 3.94 (m) |
| 21 | 13.6 | 1.77 (s) 3.63 (1H, m, overlapped) |
6'' | 63.7 | 4.36 (dd, 5.0, 12.0) |
| 22 | 123.4 | 5.55 (t, 7.0) | 4.59 (dd, 2.0, 12.0) |