Table 1.
Position | Compound 1 1 | Compound 2 2 | Compound 3 2 | Compound 4 2 | Compound 5 2 |
---|---|---|---|---|---|
1 | 13.72, s | 13.42, s | 13.44, s | 13.72, s | 13.79, s |
4 | 6.28, s | 6.24, s | 6.30, s | 6.26, s | 6.37, s |
5 | 6.80, s | 6.74, s | 6.75, s | 6.85, s | − |
11 | 3.35, d (J = 7.3 Hz) | 3.37, d (J = 7.2 Hz) | 3.36, d (J = 7.1 Hz) | 6.74, d (J = 10.0 Hz) | 3.48, d (J = 6.0 Hz) |
12 | 5.17, t (J = 7.3 Hz) | 5.17, t (J = 7.2 Hz) | 5.26, t (J = 7.1 Hz) | 5.58, d (J = 10.0 Hz) | 5.31, t (J = 7.0 Hz) |
14 | 1.77, s | 1.75, s | 1.70, s | 1.27, s | 1.79, s |
15 | 1.63, s | 1.62, s | 1.71, s | 1.28, s | 1.71, s |
16 | 4.04, d (J = 7.0 Hz) | 4.09, d (J = 7.2 Hz) | 4.15, d (J = 7.2, Hz) | 4.10, d (J = 7.0 Hz) | 3.59, d (J = 6.0 Hz) |
17 | 5.17, t (J = 7.3 Hz) | 5.18, t (J = 7.2 Hz) | 5.26, t (J = 7.2 Hz) | 5.27, t (J = 7.3 Hz) | 5.31, t (J = 7.0 Hz) |
19 | 1.71, s | 1.61, s | 1.70, s | 1.71, s | 1.87, s |
20 | 1.73, s | 1.72, s | 1.82, s | 1.82, s | 1.89, s |
3-OMe | 3.82, s | 3.91, s | |||
6-OMe | 3.97, s | ||||
7-OMe | 3.71, s | 3.80, s | 3.82, s | 3.83, s | |
1' | 8.00, d (J = 10.0 Hz) | ||||
2' | 5.79, d (J = 10.0 Hz) | ||||
4' | 1.51, s | ||||
5' | 1.51, s |
1 DMSO-d6, 2 CDCl3.