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. 2014 Apr 22;19(4):5028–5087. doi: 10.3390/molecules19045028

Table 7.

Redox potentials E (V) vs. SCE for selected RuII complexes.

Complex Oxidation Reduction
[Ru(phen)3]2+ [17] +1.27 −1.35 −1.52
[Ru(TAP)3]2+ [17] +1.94 −0.75 −0.88 −1.10 −1.60 −1.80
[Ru(phen)2(HAT)]2+ [150] +1.53 −0.86 −1.42 −1.69
[Ru(TAP)2(HAT)]2+ [150] +2.02 −0.68 −0.86 −1.08
[Ru(phen)2(PHEHAT)]2+ [145] +1.35 −1.00 a −1.25
[Ru(phen)2(HATPHE]2+ [145,151] +1.56 −0.83 −1.01
[Ru(TAP)2(PHEHAT)]2+ [145] +1.80 −0.75
[Ru(phen)2(PHEHAT)Ru(TAP)2]4+ [145] +1.39 +2.10 a −0.52 −0.76
[Ru(phen)2(PHEHAT)Ru(phen)2]4+ [157] +1.34 +1.55 −0.68 −1.06
[Ru(TAP)2(PHEHAT)Ru(phen)2]4+ [145] +1.50 +1.86 −0.57 −0.79

a poorly resolved.