Table 7.
Complex | Oxidation | Reduction |
---|---|---|
[Ru(phen)3]2+ [17] | +1.27 | −1.35 −1.52 |
[Ru(TAP)3]2+ [17] | +1.94 | −0.75 −0.88 −1.10 −1.60 −1.80 |
[Ru(phen)2(HAT)]2+ [150] | +1.53 | −0.86 −1.42 −1.69 |
[Ru(TAP)2(HAT)]2+ [150] | +2.02 | −0.68 −0.86 −1.08 |
[Ru(phen)2(PHEHAT)]2+ [145] | +1.35 | −1.00 a −1.25 |
[Ru(phen)2(HATPHE]2+ [145,151] | +1.56 | −0.83 −1.01 |
[Ru(TAP)2(PHEHAT)]2+ [145] | +1.80 | −0.75 |
[Ru(phen)2(PHEHAT)Ru(TAP)2]4+ [145] | +1.39 +2.10 a | −0.52 −0.76 |
[Ru(phen)2(PHEHAT)Ru(phen)2]4+ [157] | +1.34 +1.55 | −0.68 −1.06 |
[Ru(TAP)2(PHEHAT)Ru(phen)2]4+ [145] | +1.50 +1.86 | −0.57 −0.79 |
a poorly resolved.