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. 2014 Oct 21;19(10):16851–16860. doi: 10.3390/molecules191016851

Table 1.

Volatile compounds of red mombin (Spondias purpurea) pulp and powder stored at 0, 60 or 120 days in plastic (PP) or laminated packages (LP). Each value represents the mean ± SD (×106 chromatogram units) of three analyses of different pools.

Peak Compound RI Integral pulp Powder
After SD PP LP
(day 0) (day 60) (day 120) (day 60) (day 120)
1 hexane * >700 10.7 ± 1.3 1.2 ± 0.1 1.6 ± 0.3 1.1 ± 0.3 1.6 ± 0.5 1.3 ± 0.4
2 ethyl acetate a >700 107.5 ± 8.4 nd nd nd nd nd
3 2,3-pentanedione * >700 41.6 ± 4.3 nd nd nd nd nd
4 3,3-dimethyl pentane * >700 11.17 ± 0.47 nd nd nd nd nd
5 ciclohexane * >700 6.44 ± 0.12 nd nd nd nd nd
6 2-methyl-butanol * >700 4.01 ± 0.31 nd nd nd nd nd
7 3,4-dimethyl-pentanol * >700 4.31 ± 0.35 nd nd nd nd nd
8 1-penten-3-ol * >700 27.9 ± 6.6 nd nd nd nd nd
9 2-penten-1-ol * 793 20.1 ± 1.7 2.0 ± 0.7 1.7 ± 0.3 1.9 ± 0.5 1.2 ± 0.1 1.5 ± 0.3
10 2,3-butanediol * 794 18.2 ± 0.5 0.9 ± 0.3 1.0 ± 0.3 0.7 ± 0.1 0.6 ± 0.0 0.7 ± 0.1
11 5-hexen-2-one * 795 1.6 ± 0.1 0.9 ± 0.2 0.7 ± 0.0 0.9 ± 0.4 0.8 ± 0.1 0.7 ± 0.2
12 isopentyl acetate b 795 4.2 ± 0.1 nd nd nd nd nd
13 4-pentenal * 796 2.4 ± 0.1 nd nd nd nd nd
14 butyl ethanoate * 797 1.0 ± 0.0 nd nd nd nd nd
15 Hexanal a 801 194.2 ± 13.6 57.9 ± 10.3 45.4 ± 1.7 41.6 ± 4.9 34.1 ± 2.3 33.7 ± 3.5
16 trans-2-hexenal a 848 4.5 ± 0.3 2.8 ± 0.8 3.1 ± 1.1 1.9 ± 0.6 1.7 ± 0.2 1.4 ± 0.2
17 ethyl 2-methylbutanoate * 852 4.7 ± 0.5 2.7 ± 0.5 2.0 ± 0.0 2.1 ± 0.8 1.8 ± 0.1 1.8 ± 0.1
18 ethyl 3-methylbutanoate 857 nd 2.2 ± 0.7 2.3 ± 0.7 2.3 ± 0.4 2.2 ± 0.2 1.3 ± 1.0
19 3-hexen-1-ol a,b 858 165.2 ± 16.3 97.5 ± 7.3 88.0 ± 6.1 66.8 ± 9.4 89.3 ± 2.7 90.1 ± 8.1
20 NI 867 21.5 ± 2.3 6.0 ± 2.0 7.1 ± 2.6 6.4 ± 1.2 2.9 ± 0.0 2.7 ± 0.6
21 2,6-dimethyl-1-heptene * 870 36.9 ± 0.9 14.1 ± 2.8 15.5 ± 0.2 19.2 ± 3.9 14.4 ± 2.0 13.9 ± 1.1
22 2-hexen-1-ol a 873 114.7 ± 10.8 66.2 ± 3.8 75.6 ± 7.0 66.9 ± 6.1 71.3 ± 5.0 72.7 ± 4.4
Peak Compound RI Integral pulp Powder
After SD After SD After SD
(day 0) (day 0) (day 0) (day 0) (day 0)
23 β-pinene b 945 nd 5.8 ± 0.5 11.5 ± 4.21 13.5 ± 5.3 9.3 ± 0.1 9.1 ± 0.3
24 β-myrcene b 991 1.9 ± 0.2 nd nd nd nd nd
25 Limonene a,b 1030 14.0 ± 0.2 27.3 ± 5.4 31.0 ± 3.0 27.0 ± 5.1 23.5 ± 1.7 24.1 ± 3.3
26 Copaene b 1373 15.0 ± 1.6 nd nd nd nd nd
27 β-caryophyllene a 1415 45.2 ± 7.3 1.7 ± 0.3 1.6 ± 0.4 1.4 ± 0.4 0.9 ± 0.1 0.9 ± 0.1
28 non identified terpene 1446 2.8 ± 0.5 0.5 ± 0.0 0.5 ± 0.1 0.4 ± 0.1 0.2 ± 0.0 0.4 ± 0.2
29 α-caryophyllene a 1452 14.6 ± 1.5 0.7 ± 0.1 0.5 ± 0.1 0.5 ± 0.1 0.4 ± 0.0 0.4 ± 0.0
30 NI terpene 1470 1.6 ± 0.2 1.2 ± 0.4 0.7 ± 0.0 0.7 ± 0.2 0.6 ± 0.0 0.6 ± 0.1
31 NI terpene 1472 4.3 ± 0.1 0.2 ± 0.1 0.2 ± 0.1 0.2 ± 0.0 0.2 ± 0.0 0.2 ± 0.0
32 α-muurolene * 1494 4.8 ± 0.5 tr tr 0.4 ± 0.1 0.3 ± 0.0 0.3 ± 0.0
33 pentadecane * 1500 2.5 ± 0.1 2.5 ± 3.7 0.3 ± 0.1 0.4 ± 0.1 0.3 ± 0.0 0.3 ± 0.0
34 NI terpene 1514 8.2 ± 0.4 1.5 ± 2.2 0.3 ± 0.1 0.4 ± 0.1 0.3 ± 0.0 0.3 ± 0.0
35 NI 1615 81.9 ± 3.0 3.3 ± 2.1 4.5 ± 0.9 5.1 ± 1.4 4.8 ± 0.1 5.3 ± 0.9
36 α-bisabolol * 1683 19.2 ± 2.1 0.9 ± 0.2 0.7 ± 0.0 0.6 ± 0.2 0.9 ± 0.1 1.3 ± 0.7

RI: retention index in a DB-5 column; nd: not detected; tr: traces (>0.01 × 106 counts); NI: non identified; *: first time identified in red mombin; a: also identified by Ceva-Antunes et al. [14]; b: also identified by Augusto et al. [15].